el o Hlo o~ 130049 . o -REGD NO.D.L.33004%9 MRd m CThe @azette of India e mmumm €M fl~wv 3-39-gry @®
PART Li—Section 3—Sub-section () mtmfm . Puumnwnmm o 120) ¥ fawelt, simwrarr, wref 18, zoouw u, 1929 No. 120] NEW DELHI, ‘mnsmv, MARCH 18, 2008/PHALGUNA 28, 1929 ° mmmm st ¥ e, 18 4, 2008 LR 186(3Y) —==i wER Tt (dww) sfufrm, 1986 (1986 %1 29), 3 msaflzmzsmmmmwhmmm(m)fim lmmsfltm - w P Frerffer P et 3 gty — L (1) v P e T et (o) e B, 2008 # 1
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2. S AR .3. Ell WME 3 9_—.,‘2% 1 Wane
8. WS o, -EeIsH ® T T =
10. GO
11. GrEDIH
12. N ( ) 13, IR () 14, A= T15. uRg 16, S
17. e
18. qial
19. qATSTH 20 AtorT 51, o (©)- TRRA [ [—%10 3(i)] VTR T IS 2 STHIERY 1 2 (0} - (i
(iii) i sfgem & Frow firg (@98 o a1 i aRe G, TR S O o WS ) § fawar € HEVT WA SR B SR | Rigrd/amart oRarsemsit & fore (ot 3 Mex o aER & o #) Jvaia af- | w1 & Wl R B aon #, eore ok, sf e Ffx ¥ fore o & wwer 3 P (g W) 29 srpranT & forw afe-wme & a8 w7 winer Jawi @ s R e | enfy, g9 -uimar § food) o geR o w3 T fifl?‘ffimfl'flafiamafiwflamw AR - wE Tt et B T B 72 F, Pewrs yomen A o 2 @ @ va 3R aw @ fre 3 foe AR s smem | (@ 9 o1t @ Prive e o s & o dEReie AT v . et wn ) 3R &7 weeve & foe wigor St 1 e far smem | ¥ S| % oo o7 § wiRE o O A o R o W Aeve (e s fire wr7a) FreffRe A 3 argom s fae smeh ik | it I TS T GRT O SR SaeH & 0 do 3R i @ 9 51 sfg-ara & wmn 1.0 Rl 3 st & & | W I AEOT S S AT O Siex, I SheeiEd 7 & T aflfimfiflfi AT THR et oy & " . RN/ HegleiaEY 50 50 850 Ql{gimfl% fi i a i g 350 - 250 450 ) 350 THE GAZETTE OF INDIA : EXTRAORDINARY [PaT 11—Sec. 3(i)] 3 4 et ot i 10 5 Sl 100 50 A AAGARE | 150 - 100 . W 200 150 THiea+ a=nsad | & 5 5 ECEl = A |mefis 150 150 BREISF IWORE (H. 8) & S s | wa/ iR 1.0 ) 0.5 W WK sl . ' o J feuqor () oo g (e i ) e o8 e 3 e i e et mwfia&nfiméfimmfimfiflma&a@l
(ii) i wReoaifaeR, e 3 FEEE v s e Wfiflmmwfim%fiwmsfira@m% RS ¥ wee B foR A U e i | 59 eR B mmfimwmmfimfima o7 ¥ vw AR & S afee | ) :
(iii) m@mmmmmmm- %flfifi/filflfl%fi%fiflfiflfi?k@fifiw, mw ¥ v 9K foman FmEm | :
(iv) wmwfiafififlfifi.wdfiésflmwfiw 1 rguer, T A ¥ arftman 98% A F Roan s | {7 AR % T e T e, af g d ¥ s &, o R~ SR AT SR | : ) afingmfififimfihéfi%flwfimmma freor fear ST | o gl e W o Tuen aRaRte e afifi,fifiugmfifiwmfifima&wwmfim a o o g] T S A | uReE @ g ¥ ) oiEdE & T AU SRS | . [ 1—7ws 36)] 1 3 4 AT T Tl /e o Aiek Ifa A 8 . Tt o UReeo | 7 d BISGT SNTE | Erpgy aResoh /s s N W o ow | L LI i W fimr s | || wew< edomaaws | 500 1700 | 500 (gT3aT i) (soz) ; : o ivwor ¥ fom) L 850 (371 Bz AR B 400 450 . 350 sifearge (NO) : ol venet 100 100 . 50 : (PM) ' - TR AraTEE 400 400 300
(co) e ik 2 5 2 (NI +V) RGN, % 30 30 N Tewor: : afig@!fiflfiflfltfi-flfim#fifihflflm st sl oMl T @) s oY 3 e A | wfor fsar smer | . SmmNmtmtmwfifiafiam‘ W o & ¥R ke | oft e e Reefiy % sforder st sizor o Ry o e 06% T W e fee S | @ ww ¥ o AR Feiof drest ¥ fore dvegarer et s ome | Hrzgarer et 3 gy Rl Y s fiow e s ok & T A B Fr Y e S A aw A agnmms?er [ THE GAZETTE OF INDIA: EXTRAORDINARY [Parr I—S&t. 3()] 4 1 2 . 3 a V. <R (WK e ) et (mm%%n—lhé‘f ) 3R éfi%m(@rfiw)fifiéfifimfi%fiufiaw %afia%aa@n V. a@afimmfimam wm%m afi?fimfi?m%afifiw%a’z mafi%afim%fi Ferarar e 2 SO | T | e | S e S W (e/wfifee) s s | i gTs SR o1 aReeot | T gfawia , % 20 ¥ IR 98.7 99.5 {m=s | \ afef HS, fimfifi. 15 10 | - [as gl % 5-20 N % TS gREa % 15 o4 96 L 1 E 4 | M o AR T G | 350 250 ! et T B AT | T AraaEe e | @ ama | 150 Moo ] grATTe o AeX o B Tt i ) zoafl;rfilfiafamfimafirmfimfi qfifiasm} smfisu@m%fifiuwm mmfim | wed | mfihfizfi%%fih@fimwfimmm \ (i Wmmmflfifi mmw\ 3 1 () mmfiamfimfimfi mmmm\ flwammg,mm wmfififi &m?fl\ aflflfi?flfi'fififlflml | N [y II—avE33i)] IS TS ¢ AHYIRT T I It to alfiqaaa‘anwfisnvr:mfl@mmm‘ (1}
(2)
(i) (iif v {m (@ 430 75 T e & e Y e et 7RO o 3 gt T 297 Tl T @ it 2, @ S o e e o R o e Frerer fioz wfdm S e | e 75 ¥ 500 TICR B & AT ERYT ¥ AR o A T 109 76 el aveeser avem g wfie, S B o A e S g B e A et Spera AT Y YeITH e AT T v e ey ot v o @ e | : : - 500 TR ¥ e e et $heon & aper A T 10 @ 76 Foeh T @ B R, e B il e wa v < ) areg et o g ang Jeemr mmmfimwfimfiw 7smfiafimmflfiafisfl?wwm7GMWé : ftres BT e, an Qoo o e G o i va @ afke | ‘ AR el et <t A et e & R vt 96% 1 A T ol wfw B & e & wa aik R T AR ot A ¥er e gakan oRrg ST | IR Wit St e AR e b T e g oY o o W A S e TR A Tt o Faiie %) B & S B | e 3R @ ity w4 .8, & 3R it amRE 8 2w ¥ I @ 2000 B . wmmwwm|mma&m@w&a§mw B AR it s & & 5 s &1 20 R0 A | et & el st Fomifor Joaam ramer e aen gfiiea e S | T B ATt & 3 95% 2Bt e e R, @1 3R A e e 90% B A | - R &P o1 et 3k vever w3 Friv H ade 8o | Brllger SR APIRP-575 ot 3 e | ettty & Wy 3 57 affw e sr @ ¥ e IR T s sk w s g § sTeh wiie § OFl el @ 3 T w ) Gy St ggan & e | [Paxrll—Sec. 3()] THE GAZETTE OF INDIA : EXTRAORDINARY aregeiie Sl BT HUBRO: . 3O HERUI :
(1) vl & T R R o a ¥ aeEd At Sl (VOC) & e
99.9% a7 Y Fgaer exwen By, 3 srer R e | 2) 2@ B IS o wa | e A% o e e, SR 3 ey e 2 e Ao Regae e &9 W 9 09% I, e o fafen o &, JT= B e z-u;q:mmfiaammmw,amm.,vn.i.t.,a\mmmafiim)ai fore faemas 0% B 51 % 57 A Regger W 5 W ded el 3R 7 e e W 77w, 3R, &) S B T | (5 & gaRet & T QTS B (078 Scword Ao { drreréa st B T SR e
(i) A FE% IS,y o i s 0 99.5 R (i ) P FR % Fear, Fosr/ @ ° (iy 20 0 99.00 ST | M 9.9 ! [0} (i AR BT % Feas, Fosm oa ® () 150 fergor { s afEn & e ydsa g (i T EHsTs wiET W |
(i) S | o5 e, o, 9N, dwm ik Uz &5 7o Ten e i o Yo € A IR T b T affe e IR & j 39aRo & R7a & five wmw (9 i : suaRw T & wfife sl Frife 50 & fie sfem & e JrgEE 9o, e AR A T IR TR FEE de ede I 7 TETEE TG B | Rk SRET T R YReI & A e @ o e 3 o aed @ e AR e R fitwe stk R (oo & ¢ R SR e e | Afew o § gar o v R & ag e A # T B A | [ =8 33i)] . MR T AT ; STEHROT
(2) @ T at JeEor o v o e 2 v o e v st ah () = T (i) dger A (i) o e (V) @R @ () der el e, (vi) wibvor- Qe eaord (vil) Wb o, (vill) ardaedwEf, (i) i efes e, ok (x) ol s | 1675 S, s o/ 55 % 3t TR S ot s e R o 1 @ Ay A T & € IR S 3 vl W e weai/difet w (G IR 2w femw d) () e (il) emde ffers dmm e W @20F >robdeak (i) & frfres T e whe @ 20 & 03¥ 1obdeHda w et v & v R A 7w < 0.3 3 & v e & frfers & B s & g, 7 area 8 s ferfes Rt &Y e & wahae & w0 ¥ st & e | (s frema @ it e & & o & oo & Moo S e § Y & o et & srpem (@ o v ) Joet S R Yo @ siftrs @ B e A Wi (7,0 § & € - 469/3 95~ 017) 1995 WYY ¥ SOR SRR TSI 1 TANT I g &t T &, S e svawor e Jowet nee @ forer & wefifa & - T TR ETgRTaa T (ATaTe) Fo (Unirew) ‘ 31 TawsR) 1 S, 2000 [31, TR, |1 5, 2008 | 2008 T ¥ 2008 TF kil T/BEER 10000 5000 3000 -2000 qEaE/wE 10000 3000 2000 1000 I BT 10000 3000 2000 1000 oW aX et~ X 10 THE GAZETTE OF INDIA : EXTRAORDINARY [ParrI—Sec 30)] 6} T e R e @ Rk gea, e s v 3 R @ gE an S o & ! e e & & (Rrferas R, qea awe Reara) vy e e gt 1 e ot T S T 2, < 3 R e e | @ R st ok wew degw fem & e Peffer et & TR 3 R a3t TR 2T e 4 WO SR fepa S - JGEBROT TR @ HGRd RyeR 9z IaTas (AN & R YR 5 318 [l B WeR yaieh B aw <2% REE |ge @ m eiR Exil ¥ o 3R o 5 i | FRE EEgERA & fo Fa < 2% R Han) | e & g T B §% 15 g et Fates P Rad@ & AW HUE Wit Fatas R s | SN & TeR Re feasread Fatas T ¥, @ B TR A% TSaRiad | 24 O & W eHE & S e (&fém =) . TR EEIE Whewar e LTS Y Wow (AR AR | s forar s fe € | WE 4R W [a@n alen | qepre qBIT ffre Rfim o o <t e a e By W | aeord DI T T e B 81 | 5 1T % R - o & wow
(8) %éflhwéswa‘afimfimfiwmz%%mfififiafi%m M/mfimfimma?rr@mfi/awafi%mfi,ug T/ BRRR] 1 P T FRAA 3 T/, 3 O st L % 10% ¥ T T |
(9) mm@:mmmfifimfimm&w@m affer | el % aitys T 5 TR, WRA I SR R 37 Tee IR [T =B 3(i)] - SR T 3 TR 1 (10} an 4} — m(qwififi)maaafifiméwahma&mm?rlyd o et i fava e | el mflwmtfiefiwmfimmfifimfia. st o e & (i) g w2 aifye Ry, (u)m,wahmfifim (A2 )R wger, 3k (iil) S- e faftr | s wmtfivfi'flfi\fifitfiwmsfltwmfimfimmm =T, hfimfimfimw e & v AT S ET A § Ay A TG B aAA I SR AR | mfifimafitmfimm@mmflmfimflfimmm&fi e e | : - ifEs o, ve eRE wiw AR e gRT de A e wfkw | ot i # e e o sl ot o e | et & fore oy Sest s a1 srivr R st e | PR s Fore e svere et wr s Y Sy R | mmsflzm#fiaafi\htmmm wa@ammmflwafiw#fimmfimmmmn gonfert & wenfers aen aee (e - mwsfl’rméfi) I mflwfifimfifirfiwafiflfl(fi Wfimwwflv TR FR A gE AR | - e - mmmméfiwqfifiwflfimmfimimfi T 00% d.andr o e 70 @Y gerY & Tt sife-A IrrfYs F wE T e | Tt ot & (Rresiees PR, W g S s Y mm)fimfi.finw‘mwmmmfiafiamémfiém e @ T/ A ¥ Ry SR e gRfa o e | frew fiafimsflrmmwfirtmm@thm#fi et S T | fimagmésafimmmfi%%m%wafi mm%w o s mmmwfimsfiwmfiw 10, fifiwwafimfismmmmafim lo/Y52/0 §—3 THE GAZETTE OF INDIA : EXTRAORDINARY [Parr II—Skc. 3(i)] (@) afiufism?r (Tew EreTgs) ¥ et wn W 35, 3R I wefta wiaReait @t A fesar smem |
(ii)swwémmm* o uResdt Fw & weitm wovo 1 3k I Wt wffedt & we w Prfafa mw wen sk ufiedt W s, swefa:- * 1. U et aherveer ReR HAHS 1 2 . TOUT0 W HEATeHD I/ TIRIE T 7T Hg 1 1000 T
1. 9 3R AR 2.0
2. IO R 27 | 6.0 ERER] 50
4. Fetlad ot 8.0
5. e ) 0.14
6. PR 02
7. W8 ] 0.08
8.7 g1 ® O ¥ 60 s
9.0 5 . 16
10. TIEDORE | 1.2
1. Piage (eawdeic) 0.04 12, BT (pe) 0.8
13. S - . 004
14. URT . - 0.004 15, ST 20
16. THidet 0.4 17, arar 04
18. a15aH 0.8 19, fo 0.04
20. S50 (U)- IRRA 0.08 TEwforat.
(i) Trevtrar wafaRor ¥ o afeara (wfiman sfe-wm, wad A oot wiea AasRS e A B3, W 3nfe) ¥ fewest & fore s S ewy @ (der e @ ¥ e ¥ iR R /e ¥ wdvowrd yf o @Y a3 Brga)
(i) afera & = o = & fve (RfYfam vafaxor & fewanst & foe da wem T ¥ oy 3 e Riard/ammar srgwa 3 fae sk = s gfti fvew & Tt avewT-37eT) Juger TR A 3uaeT (SR 6 d- =, et W) wae fou o wifee | (i wgeept 2B spoET @ wore, wigen ey ot A it (24 B2t o1 o Fafda mmafiampfiflmdw%&ma)fiqasmmflmm wETE 3R e e W Y e YT A & HIWR R B e | [N I—aws 36)] ] ST T T : STERY R R T e —rom— TEE 400 / 1000 27 A | T, e et e arat R 3 g it #; daer avh ¥ Rt WP 25t AT i 75 ¥ 700 9 / 1000, 61 14 [ W, F-15017/15/2007-%rdreeey) s® %, 40, T wfew Reor:- oo e vy 5 v § aman, 844(%), 19 e, 1988 ZRY - e e & 9k B, 433 (39, i 18 3w, 1987, @T.am, 64(%), rrer 18 S, 1988, Wram, 3(a), méar 3 Sl 1980, BT, 100 (39, i 15 W, 1989, WLaLRY, 013 (%), arér 24 smm,i_sas, B 12 (%), M 8 anfi,isso, R 742 (39, e 30 s, 1990, 4w, 23 (), e 16 S, 1901, WnwnR. 9a(s1), Arlrer 21 ), 1991, WATRY, 95 (3, w12 oY, 1982, w320 (%), ardher 13 W, 1902, LRy 475 (%), W 5w, 1082, wLaTAY. 707 (), ol 1 1992, ALY 385 (3), e 28 e, 1993, WAL, 422(5), e 19 &, 1993, WAL, 801 (31), vy 51 fom, 1903, WLELRY. 176 (30, artrer 3 antm, 1996, WBLAY. 831 (%), T 31 FEER, 1907, WL 504(31), i 20 sAr, 1098, WLALRY, 7 (=), e 2 S, 1900, WAy, 662 (®, e 5 g 1999, WLBLRY, 742 (39, wrérer 25 Reewa, 2000, . 72 (s), v 6 o, 2001, WLy, se (), mfa 22 s, 2002, MBLEL 871 (31), orher 17 4, 2002, TR, 480 (), o o T, 2002, WLIN. 1088 (), AW 11 S, 2002, WL 849 (3, ardfier 30 R, 2002, LR 520 (%), rdrer 4 o7, 2005, Ty, 22 (39, ol 29 SR, 2004, WAL, 448 (9, e 12 sgen, 2004 e W f. 520 (31), w12 s, 2004, WLHLEY. 272(3), vl 5 2005, | manRL 315.(%), e 16w, 2005, WL, 484, (31, eriver 7 3T, 2008, R, 566 (31), e 26 amr, 2007 1T 37 eereyeel i s e | “ THE GAZETTEOF INDIA : EXTRAORDINARY [Parr 11—SEc. 3()] MINISTRY OF ENVIRONMENT AND FORESTS NOTIFICATION New Dethi, the 18th March, 2008 G.S.R. 186(E).—In exercise of the powers conferred by Sections 6 and 25 of the Environment (Protection) Act, 1986 (29 of 1986), the Central Government hereby makes the following rules further to amend the Environment (Protection) Rules, 1986; namely :— :
1.(1) These rules may be called the Environment {Protection) Amendment Rules, 2008.
(2) They shall come into force on the date of their publication in the official Gazette.
2. Inthe Environmefit (Prolecfion) Rules, 1986.-
(i) in Schedute -, - {a) for serial number 3, relaiing to ‘OlL REFINERY INDUSTRY' and entries relofing thereto, the following serial number and entries shall be substituted, namely:- s. | Industry Parameter Standard 4‘ No. 1 2 3 4 “3 | petroleum ol T A Efflvent Refinery . Limifing value for cancentvation (mg/! except for pH)
1. pH . 60-8.5
2. Oil & Gregse 50
3. BOD3days. 2% 150
4. COD 1250
5. Suspended Solids 200
6. Phenols
0.35
7. Sulphides
0.5
8. CN
0.20
9. Ammonia as N . 150
10. TKN 400
1. P 30
2. Cr (Hexavatent]
0.1 )
13.Cr (Total) ~ - 20 4
14.Pb
0.1
15.Hg . - 0.01 4}
16.In 50
17.Ni 10
18.Cv 10
19.V
0.2
20. Benzene - : Q.1 fiL Benzo (a] - Pyrene 02 Notes.- {i)-Concentration limits shall be complied with at the outlet, discharging effluent (excluding discharge from sea water cooling systems) to receiving environment (surface _water [ =T 3()] T 1 T ¢ SRR 15 1 3 - | 4 Bodies, marine systems or public sewers). In case of application of jreated effiuent directly- for imgation/horficulture: purposes {within of outside the premises of refinery}. make-up water for cooling systems, fire fighting, etc., the concentration limits shall alsc be complied with af the outlet before taking the effivent for such application. However, cany use in fhe process such as use of sour water in desalter Is excluded for the purpose of compliance. fi) In case of circulating seawater cooling, the blow-down from cooling systems shall be monitored for pH and oil & grease (also hexavalent & total -chromium, if chromate treatment s given to cooling water) and shall conform to.the concentration fimits for these porameters. In case of reuse of ireated effluent as cooling water make-up, all the parameters {as applicable for treated effluent}-shall be monitored and conform to the prescribed standards.
(i) in’ case of once through cooling with seawater, the ‘oil & grease content in the effluent from cooling water shall not exceed 1.0 mg/l. B. Emissions (Fumace, Limiting concentration in mg/Nm?, unless stated refineries | Boiler Sulphur Dioxide Gos” 50 50 (5O3) Liquid 1700 850 FuelType | Existing | New Refinery/Furnace/ | g Boiler and T Oxides of . Gas 350 . 250 captive Power Piant) Nitrogen (NOx) Liquid 450 350 Farticulate Matter | Gas ~ 10 5 (PM) . Liquid 100 50 Corbon Monoxide | Gas_ 150 » 100. (cO) Liguid 200 150 Nickel and Liquid 5 i 5 Vanadium [Ni+V) 5 Hydrogen Liquid / 150 150 Sulphide- (HzS) in gas fuel gas Sulphurcontent in Liquid/ 1.0 0.5 liquid fuel, weight | gas % . Notes.-
(iv) In case of mixed fue! (gas and liquid) use, the limit shafl be computed based on heat supplied by gas and liquid fuels.
(i) Al the fumaces/boilers with heat input of 10 million kilo calories/hour or mofe shall have continuous systems for monitoring of $O2 and NOx. Manual. monitoring for afl the emission parameters in such fumnaces or boilers shall be canied out once in two months.
(iii) Al the emission parameters in furnaces/boilers having heat Jorysifed Y 16 THE GAZETTE OF INDIA : EXTRAORDINARY [Pasr I—Sec. 3()] 2 3 4 input less than 10 million kilo calories/nour will be monitored once in three months. {iv) In case of continuous monitoring, one hourly Qaverage concentration values shall be complied with 98% of the time in a Month. Any concentration value obtained through manual monitoring, if exceeds the limiting concentration value, shall be considered as non-compliance,
(v) Dota on Nickel and Vanadium content in the liquid fuel (in ppm] shall be reported. Nickel and Vanadium in the liquid fuel shall be monitored af least once in six months, if liquid fuel source & quality are not changed. In case of changes, measurement is necessary after every change. {FCC Regen- Limiting concentration in mg/Nm3, unless erators) stated Existing refineries New Refinery hydro Other than | /FCC processed Hydro Commissioned FCC feed processed FCC feed Sulphur Dioxide 500 1700 500 (for hydro- (SO2) processed | feed) 850 (for other feed} Oxides of 400 450 350 Nitrogen (NOJ . Particulate 100 100 50 Matter (PM) Carbon 400 400 300 Monoxide {CO) I Nickel and - 2 5 2 Vanadium (Ni+V) Opacity, % 30 - 30 30 Notes: {i) In case part feed is hydro-processed.. the emission values shall be calculated proportional to the feed rates of untreated and treated feeds.
(i) FCC regenerators shall have continuous systems for monitoring of SOz and NO,. One hourly average concentration values shall be complied with 98% of the fime in a month, in case of continuous monitoring. Manual monitoring for all the emission parameters shall be carried out once in two months. [ I—'vs 3() ] MIRA 1 T : STENRY 17 3 i 4 1 2 .| (i) Any - concentration - value obtained through manual monitoring, if exceeds the fimiting concen"cmon value, shall be considered as non-compliance. v/ ~Data on Sulghur (weight in. %), Nickel (PPM) and Vanadium -{PPM} content in the feed to FCC shall be reported reguiarly . (V) Limit of Carbon ‘Meonoxide = emissions shal'lbe complied with except during annual shut down of CO boiler for statutory maintenance. N Plont Existing SRU Newsw«lmy capaclly Commissioned day) Sulphur Above 20 98.7 99.5 {Sulphur recovery, % : . Recovery HzS, 15 . 10 Units (SRUJ} - | mg/Nm2 . Suiphur . | 5-20 96 - 98 recovery, % . - Sulphur 1-5 94 96 recovery, % . Oxides of All capacity 35 - 250 Nitrogen (NG, mg/Nm3 Carbon All capacity 150 100 Monoxide (CO). i mg/Nm?3 Notes:
(i) Sulphur recovery units having capacity above 20 tonnes per day shall have tonfinuous systems for monitoring of SO2. Manual monitoring for ali the emission parameters shall be carried out oncein a momh‘ {ii) Data on Sulphur Dioxide’ emissions (mg/Nm?) shall be reported regularly. {iii} Sulphur recovery efficiency shall be calculated on menthly basis, using quantity of sulphur in the feed to SRU and quantity of sulphur recovered 18 THE GAZETTE OF INDIA': EXTRAORDINARY [Pary I—S&c. 3(i)] Cc- F'uglfivc Emission Storage of Volatile Liquids : General Petroleum Products
(1) Storage tanks with capacity between 4 fo 75m? and total vapour Pressure {TVP) of more than 10 kpa should have Fixed Roof Tank (FRT) with pressure valve vent. (2} Storage tanks with the capacity between 75 to 500 m? and total vapour Pressure (TVP) of 10 to 76 kpa should have Internal Floating Roof Tank (IFRT) or External Floating Roof Tank (EFRT) or Fixed Roof Tank with vapour control or vapour balancing system.
(3) Storage tanks wnth the capacity of more than 500 m? and fotal vapour Pressure (TVP) of 10 to 76 kpa should have Internal Fioating Roof Tank or External F|oqnng Roof Tank or Fixed Roof Tank with vapour control system.
(4) The tanks with the capacity of more than 75 m? and total vapour Pressure(TVP) of more than 76 kpa should have Fixed Roof Tank with vapour controt system. {5) Requirement for seals in Fioafirig Roof Tanks: {i) (o) IFRT and EFRT shall be provided with double seals with minimum vapour recovery of 96%.
(b) Primary seal shall be liquid or shoe mounted for EFRT and vapour mounted for IFRT. Maximum seal gap width will be 4 cm and maximum gap area will be 200 cm?/m of tank diameter.
(c) Secondary seal shall be rim mounted. Maximum seal gap width will be 1.3 cm and maximum gap area wif be 20 cmZ/m of tank diometer. {d) Material of seal and construction shall ensure high performance and durability.
(i) Fixed Roof Tanks shall have vapour control efficiency of 95% and vapour balancing efficsepcy of 90%. {iiiy Inspection and maintenance of storage tanks shall be caried out under strict control. For the inspection, API RP 575 may be adopted. _In-service inspection with regard seal gap should be caried out once in every six months and repair to be implemented in short time. In future, possibility of on-stream repair of both seals shall be examined. Storage of Voldtile liquids : Benzene Storage *
(1) FRT with vapour to incineration with 99.9% of removal efficiency for volatile crganic compounds (VOC) shall be provided.
(2) IFRT/EFRT with double seals, emission-reducing roof fitting and fitted with fixed roof with vapour removal efficiency of at least 99% shall be provided. [am—avE 3] IR T O SR (y 2 3) (4}
(5) Solvents for Lube-Base Of producHon (Furfural, NMP, MEK, Toluene and MIBK) IFRT with double seals and inert gas blcnk'efir\g with vapour removal efficiency of at least 97% shall be provided. {Emission control for Road Tank truck/ Rail tank wagon loading . Loading of | Gasoline and Naphtha: ’ Volatile {i) vOC reduction. % i) 99.5 “Products
(i) Emission. gm/m?3 i) S Benzene: {iy vOC reduction, % i 99.99 | i) Emission, mg/m? (i) - 20 Toluene/Xylene: i) VOC reduction, % W 9998
(ii) Epmission, mg/m? (i) 150 M Note: W It shail be applicable for Gasoline, Naphtha, Benzene. < Toluene and Xylene loading. {i)) Road tank Truck shalt have Bottom loading and Rail tank wagon shall have Top submerged loading. (it} Annual leak testing for vapour cqlleclion shall be done. standards for Equipment Leaks Approach: Approach for controlling fugitive emissions from equipment leaks shall have proper selection, instaliation and maintenance of non-eaking or leak-fight equipment. Following initial testing after commissioning, the monitoring for leak detection is to be caried out as a permanent on-going Leak Detection and Repair (LDAR) programme. finally detected leaks are to be repaired within olkowable time frame. . Compoenents to be Covered: Components that shall be covered under LDAR - programme include {i) ‘Block valves; (i) Control . valves; fii} Pump secls;” {iv] Compressor _sea\s; (v) Pressure relief ‘valves: [vi) Flonges - Heat Exchangers: (vil) Flanges - Piping; (viil) Connectars - Piping; (ix} Open ended lines; and (x) Sampling connections. Equipment ond line 'sizes more than 1.875 cm or % inch are fo be covered. : Applicability: LDAR programme would be applicable to components {given at 2 above) for following sproducts/compounds:
(i) hydsocarbon gases; (i) Light liguid with vapour pressure @ 200C > 1.0 kPa:; and {ii) Heavy liquid with vapour pressure @ 20°C between 0.3 to 1.0kPa. While LDAR will not be applicabie for heavy liquids with vapour pressure < 0.3 kPa, it will be desirable to check for liquid dripping as indication ofteak. Definition of leak: Aleakis defined s the detection of VOC concentration more than the. values (in ppm) specified pelow at the emission source using a hydrocarbon analyzer according to measurement profocol (US EPA - 453/R-95-017, 1995 Protocol for equipment leak emission estimdtes may be referred to: THE GAZETTE OF INDIA : EXTRAORDINARY [ParT II—Skc. 3(i)] Component General Hydrocarbon (ppm) | Benzene (ppm| Til 31¢ Dec. | w.ef. January | TH 31+ Dec. | welf. 2008 01, 2009 - 2008 ) January ‘ 01, 2009 Pump/Compressor | 10000 5000 3000 2000 Valves/Flanges 10000 3000 2000 1000 Other components | 10000 3000 2000 1000
(6) In addition, any component observed to be leaking by sight, sound or smell, regardless of concentrafion {liquid dripping, visible vapor leak) or presence of bubbiles using soap solution should be considered as leak.
(7). Monitoring Requirements and Repair Schedule: Following frequency of monitoring of leaks and schedule for repair of leaks shiall be followed: . Component Frequency of monitoring ~ | Repair schedule Quarterly (semiannual Repair will be started within 5 after two consecutive working days and shall be periods with < 2% leaks completed within 15 working and annual - after 5 | days after detection of leak for perieds with < 2% leaks) general hydrocarbons. In case Pump seals Quartery of benzene, the leak shall be Compressor sedls Quarterly attended immediately for Pressure relief Quarterly repair. devices : Pressure relief Within 24 hours devices {after . venting} ) Heat Exchangers Quarterly Process drains Annually Components that Annually are difficult to monitor Pump seals with Immediately Immediately visible liquid ’ dripping Any component Immediately Immediatelywith visible leaks Any component Within five days - after repair/replacement
(8) The percentage leaking components should not be more than 2% for any group of components, monitored excluding pumps/compressors. In case of pumps/compressors, it should be less than 10% of the total number of pumps/compressors or three pumps and compressors, whichever is greater.
(9) Emission Inventory: Refinery shall prepare an inventory of equipment components in the plant. After ‘the instrumental measurement of leaks, emission from the components will be calculated using stratified emission factors {USEPA) or any other superior factors. The total fugitive emission will be established. {10} Monitoring: Following types of monitoring methods may be Judiciously employed for delection of leaks: (i) Instrumental method of measurement of leaks; (i) Audio, visual and olfactory (AVO) leak detection; and {iii) Soap bubble method. [wnn—wfi 331 NRE 1 TR 2 SR : 21
(11) Data on time of measurement and concentrafion value for leak detection: time of repair of leak; and time- of measurement & concentration value after repair of leak should be documented for all the compenents.
(12) Pressure relief and blow down systems should discharge to a vapour collgbtim and recovery system or fo flare. . .
(13) Open-ended lines should be closed by’a blind flange or plugged;
(14)" Totally closed-loop should be used in alt routing samples.
(15) Low emission packing shod!d be used forvalves.
(18) High integrity sefi"ng materidls should be used for flanges. D. Emission Standards for VOC from Wastewaiter Collection and Treatment
(1) Al contaminated and odorous.wastewater streams shall be handied in closed systems from. the source to the primary freatment stages (oilwater “separator and equalizafion fanks).
(2) - The collection system shall be covered with tha seals {traps) on sewers and drains and gas tight covers on junction boxes. {3) Oil-water separators and equaiization tarks shall’ be provided with floating/fixed covers. The off-gas generated shall be freated to remove af least 90% of VOC and eliminate odour. The system design shall ensure safety {prevention-of formation of explosive mixture, possible detonation” and -reduce the impact) by dilution with airfinert gas, installing LEL detector including control devices, seal drums, detonation anestors, etc. The system shall be designed.and operated for safe maintenance of the collection and primary treatment systems.
(4) » Wastewater from aromatics. plants (benzene and xylene plants) shall be treated to remove benzene & total aromatics to a level of 10, 20 ppm respectively béfore discharge to effiuent freatment system without dilution.”’
(b) Serial number 35, velc'ing‘lo *oil refineries, (sulphur oxide) and entries relating theteto shall'be omitted; {i) inSchedule VI, inPart C, - {a) serial number ? relating to “Oil Refinery Industry’ and entries relafing theteto, the following serlal number and entries shall be substituted, namely :- “1. Peroleum Oll Refinary :, Paramedier Standard ' 1 - 2 Quantum limit in Kg/ 1,000 fonne of crude processed R
1. Oil & Grease 20 . -
2. BOD3goy. 2% 60
3. CoD c 50
4. Suspended Solids 80
5. Phenols 0.14
6. Sulphides 0.2
7. CN 0.08
8. Ammonia as N 6.0 i
9. TKN 16
10. P 12
11. Cr [Hexavalent) 004
12. Cr (Total) 08
13.Pb 0.04 THE GAZETTE OF INDIA : EXTRAORDINARY [Part I—Skc. 3()] Parameter : Standard .- 1 2 Quantum limit in Kg/ 1,000 tonne of crude processed
14. Hg 0.004 )
15.2n . . 20
16. Ni N 04
17.Cu 04
18.V 0.8
19. Benzene 0.04
20. Benzo (a) - Pyrene 0.08 Notes :
(i) Quantum limits sholl be applicable for discharge of total effiuent {process effluent, cooling water blow down including sea cooling water blow down, washings, etc.) to receiving environment (gxcluding direct apglication on land for imgation/horticulture purposes within the premises of refinery).
(i) In order to measure the quantity of effiuent (separately for discharge to receiving environment, application for imgation/horticulture purposes within the premises of refinery & blow-down of cooling systems), appropriate fiow measuring devices (e.g. V-notch, flow meters) shall be provided with. (i} Quantum of pollutants shall be caiculated on the basis of daily average of coneentration values (one 24-houry composite sample or average of three grab samples, as the case may be), average flow of effluent during the day and crude throughput capacity of the refinery. =+ .
(iv) Limit for quantity of effiuent discharged fexcluding blow-down from seawater cooling) shall be 400 m3/1000 tonne of crude processed. However, for refineries " | located in high rain fall area, limit of quantity of effluent only during rainy days shall be 700 m3/1000 tonne of crude processed.”. [F. No. Q-15017/15/2007-CPW] R. K. VAISH, Jt. Secy.
Note : - The principal rules were published in the Gazette of India vide number S.0. 844 (E) 19" November, 1986 and subsequently amended vide S.0. 433 (E) dated 18" April, 1987, S.0. 64 (E) dated 18" January, 1988, 5.0. 3 (E) dated 3" January, 1989, S.0. 190 (E) dated 15" March, 1989, G.S.R. 913 (E) dated the 24" October, 1989, S.0. 12 (E) dated the 8" January, 1990, G.S.R. 742 (E) dated the 30" August, 1990, S.0. 23 (E) dated the 16" January, 1991, G.S.R. 93 (E) dated the 21% February, 1991 G.S.R. 95 (€) dated the 12" February, 1992, G.S.R. 329 (E) dated the 13® March, 1992, G.5.R. 475 (E) dated the 5" May, 1992 G.S.R. 797 (E) dated the 1% October, 1992, G.S.R. 386 (E) dated the 28" April, 1993, g.s.r. 422 (e) dated the 19™ May, 1993, G.S.R. 801 (E) dated the 3t* December, 1993, G.S.R. 176 (E) dated the 3" April, 1996, G.S.R. 631 (E) dated the 31 October, 1997, G.S.R. 504 (E) dated the 20" August, 1998, G.S.R. 7 (E) dated the 2" January, 1999, G.S.R. 682 (E) dated the 5" October, 1999, G.S.R. 742 (E) dated the 25" September, 2000, G.S.R. 72 (E) dated the 6™ February, 2001, G.S.R. 54 (E) dated the 22™ January, 2002, G.S.R. 371 (E) dated the 17 May, 2002, G.S.R. 489 (E) dated the 9™ July, 2002, S.0. 1088 (E) dated the 11™ October, 2002 and G.S.R. 849 (E) dated the 30% December, 2002, G.S.R. 520 (E) dated 1% July, 2003, G.S.R. 92 (E) dated 25" January, 2004, G.S.R. 448 (E) dated 12" July, 2004, Corrigenda G.S.R. 520 (E) dated 12* August, 2004, GS.R. 272 (E) dated 5™ May, 2005, G.S.R. 315 (E) dated 16" May, 2005, G.S.R. 546 (E) dated 30" August, 2005, G.S.R. 46 (E) dated 3" February, 2006, G.S.R. 464 (E) dated 7 August, 2006 , G.S.R. 566 (E) dated 29 August, 2007 and G.S.R, 704 (E) dated 12" November, 2007. Printed by the Manager, Govt. of India Press, Ring Road, Mayapuri, New Delhi-110064 and Published by the Controller of Publications, Delhi-110054.