Tt Ho Flo Tee-33004/99 REGD. NO. D, L.-33004/99 Che Gazette of India EXTRAORDINARY AT J1—EUS 3-—I9-WUS (i)
PART [I—Section 3—Sub-scction (i) it & gl PUBLISHED BY AUTHORITY . 578] ¢ Taeel, YEhaR, TaET 9, 2012/FiaH 18, 1934 No. 578) NEW DELHL FRIDAY, NOVEMBER 9, 2012/KARTIKA 18, 1934 vl T @ wA sfagern % fewett, 9 o, 2012 A, 820(3%).—F WHR, vafatol () sfufram, 1986 (1986 F 29) T 94 6 @R 25 F e ww wfrrat &1 wE @ g, v (we) fraw, 1986m3fi7xf¥flmmfiafifmfiwfifiafifiwwfié,ww:— 1 (1) g1 Pl =7 e m wafoeor (fen) (ster T Fram, 2012 3 1
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(2) TEmIfET & wa W de @ AEvIF T W varlw g |
(3) FHET il ARgs & A S AT TeRgEE (PA) MR TERIRS (MA) ifers av (PTA) she sifireger SoRiz (DMT) 39w 3 Hre) = 2 wilfer g W | A A SIS @ AT S PA/MA Teiad T 3 R s 30,000 BREGEIRELE i tuio il e R DR I 8 SR g m@zfimflw%fiqwfim}o%fié?flfimfimfi\ 4279 Gi/2012 1) THE GAZETTE OF INDIA : EXTRAORDINARY [ParT 11—SEC. 3(i)] (wle T o w T Seeea (R wewe) = T W LA, AP o e # radame o | e /Ao e qur ot 10 0] TG e | SER /Ao vene aur #iEwT 30 30 H BT Hanfar HURNE S T, ChaNeE e, 75 75 FeFEH Tl Teie Fewss | Auar Rdiede, ifewa e 05 05 FHAAT @R31S) A (wardang) e o1 [l RIS WiEASs | GhegEe e 10 10 (HCN) .
AIAA(HAPs)- FBE, Bremseia R e 318- 0.1 o1 BEE IR SIS (WD) T THHS A (HAPs), HSH, e vae 5.0 5.0 dh= R qera A (HAPs), &30 Aréves, ST, T, Qran coe 20.0 10.0 &30, e, S8, e 3R dra AT At T ?m,m 3t &g caie 50 25 W S (A SEE) /T g e A, aetw g atex 3 A3 (v, die 3 AT, div, fRare tee 20 Rparer) A M, T, Fursa Ao (&), v, 100 afeas, sreha, erfeas, e, AR, &S 3 dish) | coafesr, £5h, st T A3 (et Qefterer | aier-Fer, wer 750 HR o) (ftne), defter, fifew . —_— T«T‘TIZ .
feruqor— HAP- TRESCHT a1y Teuds s B ¥ 3120aT 354 a1k Fareesr wamat srerar wafavofar 3iv SN forRe TTal oY 9fdge IR s R | L9 [—avs 3(i)] WA =1 TSI SEIR0 3
5. WEE 3ot & fow A TN Za BT HUSRVT: HTYROT Wil dgarasr 3eme
(1) 4875 aealie & dlie T 73TaT aTet HUSROT o 31X P aToq qaTT & Reo urE F 30F B W, SHF o e gl T R e e wfd g At | @ 75 A 500 EAIEY Y BT AT HUSROT E AN T ATST ZaTa 10 I 76 el UTeper & v @Y R, FHRT Tl AR et St arer Al @t i arew B Asrar srerar ATy T woTe wf warf g arfew () 500 T & HIE e At HOSROT EF AN et arew g 10 F 76 el T & dre @ W, SHET T AR Xl J19ar and et @i s arsy e qom wfa w2 el afw | () 75 IR T 3HTH era aret Ep 3N e AT g 76 e o @ H0F @A W, sE o ARl 3R arew Fepere voel Wit R |
(5) welfcar o darelt Eftpat o) et e Y Haawar:
(i) (&) (=) ) (%)
(i)
(iii)(@)
(iv) T Ay IeaRe FATET B N A wefiT oe 96% H FgAwe Ay Ay g it wrorrelt afe &t wirer AR awd St | T wellie o A A WA W FT F 31U ST B v 7 @i HY 3l waer o HE QM | whier 1o Y 3rfUevaay DS 4 . @ 3R e s B E T & 200 9 Y. /et g | ToT Wiver Rt ax A eplt | e e Y srfiede die 1.3 . @i ik sRas Headrel 81T £ & eara @20 3 Q. /e g | Hirer S wradt 3R ot seaes Rvurea e aren @, tar ghfea R s | FUT T arel Eep Y Ao TeRi0T FRAC 95% B 3T a15a Heceret FerwET 90% B | HUSROT et o fadiator 3 Tw- 1@ w2 forrEor & reher gamy fafiaror & fre APL RP 575 &) Huamar I | ) @ & S et 3 & Hely 3 e o 7R F ww ar B FAA AT A Ien |Hg F Hrarf | aifrsT 3 Qe Wl Y AEIT B BHE B ST UEA S AN @ & e A ST | FUECTAT WG 873 HUAT UTeTvaT Y (gt 3UBRUT &Y &1 Wibg o7 & Yo Rpar aira | THE GAZETTE OF INDIA : EXTRAORDINARY [ParT TI—Sec. 3(i)] ) ) &, o=, dredrear a7 THTS & VSR TRl T arel ¥ F welEtor & aea & o aomie Frfae A (voce) g 7371 99.9% @, WareT & AR, rar I B Wl Rl oA/ /AT R o (METHIRE/STEIRE) el W, seaed =pheor oa B we Geel HR S TURN o & WY aTST QUSRI SHAT BT F B 99% B, e P SRt rrar ’ w2l 3R R o F fE eaRs Kt o HR Arsgiee TR H FImar F (W & B, oA 47, 4T AU & fAU Scieid i) T amaha scuret | ua: - &y T (i) voC weldro% (i)299.5 FogaT ECCh
(ii) 3cTid, TTH /gTHT (ii)<S deeha aun e o
(i) voC el % (i)299.99 kibc Fuar
(ii) ewor, foam aasfier (ii)<20 eifedd /Arsale:
(i) VOC @i % (i)299.98 Eiici e
(i) seolel, Fram. semefied | (5150 "1 o | (@ I vi, Wy ST e - M - & 3, 1L HR/AE e e Fr wfit oF - wd FET 8§ T ST AU Y Hag wREE & uvar] et s geate Ak aRfar wh SRR, 3 - EZANE e e ) T B e E Y (3T 3T cemet 3 A arefdin) A (Ir./8ve) [ Frfam fafam @or | e weEges (ML.T) ddss TAEIIISS (VW) eifed=-arg- 100 ewEEAe (ELELAS.) T wha s VOC-HAPs feaaa-AEAEEae (G1.8.37% ) (PN, vAiam) s séRpeTge, SIERIATET 0.5 (THHE) TelT Uehal SeqolT B o VOC-HAPs (@wsfie | deahi, TYCTETE Celle TRH 3eToie . o SeTETEA) I o N T VOC-HAPs (831, | 33, draftear, $8mM, wefiear, drah cetie - w00 | T, i) 9 0z 3)) STRE T ToTH ; SREIROT 5 WA 3 $oli- Saseler semsdier, drN-Ofieha TeTsde, Sat-Sunseher amaTss, drdvea-REre FANIES MR, S -SUTSAT 575 T, ThuaT-varseETEe, B, widrehe HIFEES, TIET- FREISIe WSS " | [ ¥ ,-15017/12/2008-Ff 559, ] o ST, W A OO e SR R % T H LA 844(3), AN 19 TR, 1986 B B FHIUE W o 3K 68 W L3433 (37) AW 18 370 1987; A 3f gel HELALR 512 (3), ATl 9 S[ETS 2009; ALHLEA 543 (31), A 22 S[ETE 2009; WAL 595 (31) AW 21 FET 2009; THLE 794 (37) AT 4 T 2009;
HLEL 826 (31) AW 16 TAET 2009; AL 01 (31) TG | ST 2010; FLALR 61 (31) TG § Wl 2010; VLA 485 (37) AW 9 5T 2010; WLALRA 608 (37) AT 21 TS 2010; THLR 739 (31) A 9 eFT 2010; WLAT.FA 809 (31) AW 4 IR 2010; ALAHLEY 215 (3r) aw 15 JF 2011 WAL 221
(37) aTrE 18 FE 2011, WLALRY 354 (31) AW 2 7 2011, WLALE 424 (31) G 1 SeT 2011; AL 446 (37) aW 13 S 201; FLHLE. 152 (31) e 16 A 2012; WA, 266 (31) ariE 30 7 2012 R aranfd 277 (3n) arlm 3190 2012 & gRTSEH Heaa BRI MINISTRY OF ENVIRONMENT AND FORESTS NOTIFICATION New Delhi, the 9th November, 2012 GS.R.820(E)— In exercise of the powers conferred by sections 6 and 25 of the Environment (Protection) Act, 1986 (29 of 1986), the Central Government hereby makes the following rules further to amend the Environment (Protection) Rules, 1986, namely:-
1. (1) These rules may be called the Environment (Protection) Fourth Amendment Rules, 2012.
(2) They shall come into force on the date of their publication in the Official Gazette.
2. In the Environment (Protection) Rules, 1986,- (@) in Schedule I, in the entries against serial number 38 relating to ‘Petrochemical (Basic and Intermediates),-
(i) in the entries under column 2, for the word “EFFLUENT®, the letter and word “A.
Effluent” shall be substituted;
(ii} at the end, the following entries shall be inserted, namely:- S. No. Industry Parameter Standards ¢} @ 3 @ B. Emission from Chimney / Stack Limiting concentration in mg/Nm’, unless stated Fuel Type | Existing New plants / Expansion of “(Furnace, Plants Existing Plant Boiler, Sulphur Dioxide Gas 50 50 Heater, (80 Liquid 1700 850 Vaporiser) Oxides of Nitrogen | Gas 350 250 NOx) Liquid 450 350 Particulate Matter | Gas 10 05 (PM) Liquid 100 50 4279 G2f12-2 6 THE GAZETTE OF INDIA : EXTRAORDINARY [Pary 11—Skc. 3(1)] 0] @ [6) | @ !
Carbon Monoxide | Gas . 150 100 (€O Liquid 200 150 Note,- [0 All values shall be corrected to 3% Oxygen.
(i) Wet scrubber shall necessarily be operated at the time of decoking.
(iify Norms for CO shall be monitored only in case of Phthalic Anhydride (PA), Maleic Anhydride (MA), Terephthalic’ Acid (PTA) and Dimethyl Terephalate (DMT) Plants. Norms for CO emissions shall not be applicable to PA/ MA manufacturing standalone existing plants with an installed capacity of less than 30,000 metric tonnes per annum, provided that such units have a chimney/stack of minimum 30 metres height for emitting Carbon Monoxide.
Process Emission (Specific Pollutant) Source Limiting concentration in mgNm® Exiting New. Plants Plants Chlorine EDC/VCM Plant and 10 10 Incinerator Hydrochloric Acid Mist | EDC/VCM Plant and 30 30 Incinerator Ammonia Wastewater stripper, 75 75 acrylonitrile plant, caprolactum plant Hydrogen Sulphide Naphtha pre-treatment 05 05 _plant, olefin plant Phosgene (TDI) and (MDI) plant o1 ol Hydrogen Cyanide(HCN) | Acrylonitrile plant 10 10 VOC (HAPs)- TDI and TDI, Methylenedipheny] 0.1 0.1 MDI Di-isocyante (MDI) Plants VOC (HAPs), Benzene Benzene, Butadiene Plants 5.0 5.0 and Butadiene VOC (HAPs), EO, VCM, | EO, VCM, EDC, ACN, PO 200 100 EDC, ACN and PO Plants . Organic Particulate PA, MA and TDI Plants 50 25 Process Emission (General Pollutant) Source LimifinF concentration in mg/Nm VOC (MA, PA and MA, PA, Phenol Plants 20 Phenol) VOC (EB, Styrene, Ethyl benzene (EB), 100 Toluene, Xylene, Styrene, Toluene, Xylene, Aromatics, EG and PG) Aromatics, EG, PG Plants VOC (paraffin, Acetone | Non-methane, HC 150 and Olefins) (paraffin), Acetone, Olefins Plants NOTE— HAP - Hazardous Air Pollutants are those pollutants that cause cancer or other serious health effects, or adverse environmental and ecological effects.
C. Standards for Fugitive Emission Storage of Volatile Liguids: General Petrochemical / Petroleum Products.
(1) Storage tanks with capacity between 4 to 75m’ and total vapour pressure (TVP) of more than 10 kpa should have fixed roof with pressure valve vent.
[T 11—380E 3(3)] MRA F1 TATH : AFHRO] 7 (0] 4 ) Storage tanks with capacity between 75 to 500 m’ and total vapour pressure (TVP) of 10 to 76 kpa should have internal floating roof or external floating roof or fixed roof with vapour control or vapour balancing system.
Storage tanks with the capacity of more than 500 m® and total vapour pressure (TVP) of 10 to 76 kpa should have internal floating roof or external floating roof or fixed roof with vapour contro] system.
The tanks with the capacity of more than 75 m® and total vapour pressure (TVP) of more than 76 kpa should have fixed roof with vapour control system.
Requirement for seals in Floating Roof Tanks- () (a) Internal Floating Roof Tank (IFRT) and External Floating Roof Tank (EFRT) shail be provided double seals with minimum vapour recovery of 96%.
(b) Primary seal shall be liquid or shoe mounted for EFRT and vapour mounted for IFRT. Maximum seal gap width will be 4 cm and maximum gap area will be 200 em?m of tank diameter.
(c) Secondary seal shall be rim mounted. Maximum seal gap width will be 1.3 cm and maximum gap area will be 20 cm*/m of tank diameter.
(d) Material of seal and construction shall ensure high performance and durability.
(i) Fixed roof tanks shall have vapour control efficiency of 95% and vapour balancing efficiency of 90%.
(iii) (a) inspection and maintenance of storage tanks shall be carried out under strict control;
(b) for the inspection, API RP 575 may be adopted;
(c) In-service inspection with regard seal gap should be carried out once in every six months and repair to be implemented in short time; and
(d) the possibility of on-stream repair of both shall be examined.
(iv) Storage tanks shall be painted with white colour shade, except for derogation of visually sensitive area.
D, Storage of Benzene, VCM and ACN FRT with vapour for incineration with 99.9% of removal efficiency for volatile organic compounds (VOC) shall be provided; or IFRT/EFRT with double seals, emission-reducing roof fitting and fitted with fixed roof with vapour removal efficiency of at least 9% shall be provided; or Internal floating roof and nitrogen blanketing in between fixed and floating roofs shall be provided.
u279 dfi//z -3 THE GAZETTE OF INDIA : EXTRAORDINARY [ParT li—Sgc. 3(i)] (Emission control for Road tank, truck / Rail tank, wagon loading) Naphtha:
Loading (i) VOC reduction, % (i)299.5 of or or Volatile (i) Emission, gm/m’ (i) <5 Products Benzene and Butadiene:
(i) VOC reduction, % (i) 299.99 or or
(ii) Emission, mg/m® (i) <20 Toluene/Xylene:
(i) VOC reduction, % (i)299.98 or or
(ii) Emission, mg/m’ (i) < 150.".
(b) in Schedule VI, in Part D relating to General Standards, in the entries under item 1II relating to Load/Mass based Standards, after serial number 8 relating to *Glass Industry’ and entries relating thereto, the following serial number and entries shall be inserted, namely :- S. Industry Parameter Standard No.
“9 Petrochemicals Source Quantum limit in (Basic and gm/hour for New/ Intermediates) Expansion Plants (gm/hr) Organic Phthalic anhydride (PA), 100 Particulate Maleic anhydride (MA), Toluene Di-isocyanate (TDI) plants — process emission VOC-HAPs (Toluene Di-isocyate) TDI, 0.5 (TDI + MDI) Methylenediphenyl Diisocyante (MDI) Plants- Process emission VOC-HAPs Benzene, Butadiene Plants — 25.0 (Benzene + | Process emission Butadiene) VOC-HAPs EO, VCM, EDC, ACN, PO 50.0 (EO, VCM, Plants — Process emission EDC, ACN + PO) Abbreviations: EG — Ethylene Glycol, PG — Propylenc Glycol, EO — Ethylene Oxide, VCM — Vinyl Chloride Monomer, EDC - Ethylene Di Chloride, ACN — Acrylonitrile, PO — Propylene Oxide, HCN — Hydrogen Cyanide.”.
[F. No. Q-15017/12/2008-CPW] AJAY TYAGH, Jt. Secy [wm 1—wevs 3(i)] RUSEEAIELE B | 9 Note— The principal rules were published in the Gazette of India vide number 8.0. 844 (E), 19" November, 1986 and subsequentty amended vide notifications numbers 8.0. 433 (E), dated 18" April 1987; G.S.R. 97 (E), dated the 18" February, 2009; G.S.R. 149 (E), dated the 4" March ,2009; G.S.R. 512 (B), dated the 9" July, 2009:G.S.R. 543 (E), dated the 22" July, 2009; G.SR. 595 (E), dated the 21* August, 2009; G.S.R. 794 (E), dated the 4" November, 2009; G.S.R. 826 (E), dated the 16" November, 2009; G.S.R. 01 (E), dated the * January, 2010; G.SR, 61 (E), dated the 5" February, 2010; G.S.R. 485 (E), dated the 9" June, 2010; G.SR. 608 (E) dated the 21% July, 2010; GS.R. 739 (E), dated the 9" September, 2010; G.S.R. 809(E), dated, the 4" October, 2010, G.S.R. 215 (E), dated the 15" March, 2011; G.SR. 221(E), dated the 18" March, 2011, G.S.R. 354 (E), dated the 2 May, 2011; G.S-R. 424 (E), dated the 1 June, 2011; G.SR. 446 (E), dated the 13" June, 2011; G.SR. 157 (E), dated the 16" March, 2012; G.S.R. 266(E), dated the 30 March, 2012; and G.S.R. 277 (E), dated the 31 March, 2012, Printed by the Manager, Goverament of India Press, Ring Road, Mayapuri, New Delhint 10001 and Published by the Controlier of Publications, Delhi-110054