(1) The Central Crisis Groups shall provide information on request regarding chemical accident prevention, preparedness and mitigation in the country;
(2) The State Crisis Group shall provide information on request regarding chemical accident prevention, preparedness and mitigation to the public in the State;
(3) The Local Crisis Group shall provide information regarding possible chemical accident at a site in the industrial pocket and related information to the public on request;
(4) The Local Crisis Group shall assist the Major Accident Hazard installations in the industrial pocket in taking appropriate steps to inform persons likely to be affected by a chemical accident.
977 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
SCHEDULE-1 [See rule 2(b) & 2(j)]
PART – 1
(a) Toxic Chemicals : - Chemicals having the following values of acute toxicity and which owing to their physical and chemical properties, are capable of producing major accident hazards:
__________________________________________________________________ Sl. Degree of Oral Toxicity Dermal Inhalation No. Toxicity LD 50(mg/kg) Toxicity toxicity by (Dermal LD50) dust & mists (mg/kg) ( mg/l) ________________________________________________________________________ 1 Extremely 1-50 1-200 0.1-0.5 toxic
2. Highly Toxic 51-500 201-2000 05.-2.0
(b) Flammable Chemicals :- (i) Flammable gases: chemicals which in the gaseous state at normal pressure and mixed with air become flammable and the boiling point of which at normal pressure is 20 o C or below;
(ii) Highly Flammable liquids: Chemicals which have a flash point lower than 23 o C and the boiling point of which a normal pressure is above 20 o C;
(iii) Flammable liquids: chemicals which have a flash point lower than 65 o C and which remain liquids under pressure, where particular processing conditions, such as high pressure and high temperature, may create major accident hazards.
(c) Explosives: Chemicals which may explode under the effect of flame, heat or photo-chemical conditions or which are more sensitive to shocks or friction than dinitro-benzene.
978 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
PART II LIST OF HAZARDOUS AND TOXIC CHEMICALS S.No. Name of the Chemical
1. 2.
1. Acetone
2. Acetone cyanohydrine
3. Acetyl chloride
4. Acetylene (Ethyne)
5. Acrolein (2-propenal)
6. Acrylonitrile
7. Aldicarb
8. Aldrin
9. Alkyl phthalate
10. Allyl Alcohol
11. Allylamine
12. Alpha Naphthyl Thiourea (ANTU)
13. Aminodiphenyl, -4
14. Aminophenol-2
15. Amiton
16. Ammonia
17. Ammonium Nitrate
18. Ammonium Nitrates in fertilizers
19. Ammonium sulfamate
20. Anabasine
21. Aniline
22. Anisidine-p
23. Antimony and compounds
24. Antimony Hydride (Stibine)
25. Arsenic Hydride (Arsine) 979 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
26. Arsenic Pentoxidi, (Arsenic) (v) Acid and Salts
27. Arsenic Trioxide, Arsenious (iii) Acids and Salts
28. Asbestos
29. Azinphos-Ethyl
30. Azinphos-Methyl
31. Barium Azide
32. Benzene
33. Benzidine
34. Benzidine Salts
35. Benzoquinone
36. Benzoyl Chloride
37. Benzoyl Peroxide
38. Benzyl Chloride
39. Benzyl Cyanide
40. Beryllium (Powders, Compounds)
41. Biphenyl
42. Bis (2-chloromethyl) Ketone
43. Bis (2,4,6-Trinitrophenyl) Amine
44. Bis (2-chloroethyl) Sulphide
45. Bis (Chloromethyl) ether
46. Bis(tert-Butylperoxy) Butane, -2,2
47. Bis(tert-Butylperoxy) cyclohexane, 1,1
48. Bis, 1,2 Tribromophenoxy-Ethane
49. Bisphenol
50. Boron and compounds
51. Bromine
52. Bromine Pentafluoride
53. Bromoform
54. Butadiene 1,3
55. Butane
56. Butanone-2 980 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
57. Butoxy Ethanol
58. Butylglycidal Ether
59. Buty peroxyacetate, tert
60. Butyl peroxyisobutyrate, tert
61. Butyl peroxy isopropyl carbonate, tert
62. Butyl peroxymaleate, tert
63. Butyl peroxypivalate, tert
64. Butyl vinyl Ether
65. Butyl-n-Mercaptan
66. Butylamine
67. C9 Aromatic Hydrocarbon Fraction
68. Cadmium and Compounds
69. Cadmium oxide (fumes)
70. Calcium Cyanide
71. Captan
72. Captofol
73. Carbaryl (Sevin)
74. Carbofuran
75. Carbon Disulphide
76. Carbon Monoxide
77. Carbon Tetrachloride
78. Carbonphenothion
79. Cellulose Nitrate
80. Chlorates (used in explosives)
81. Chlordane
82. Chlorfenvinphos
83. Chlorinated Benzenes
84. Chlorine
85. Chlorine Dioxides
86. Chlorine Oxide
87. Chlorine Trifluoride 981 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
88. Chlormequate Chloride
89. Chloroacetal Chloride
90. Chloroacetaldehyde
91. Chloroaniline, –2
92. Chloroaniline,–4
93. Chlorobenzene
94. Chlorodiphenyl
95. Chloroepoxypropane
96. Chloroethanol
97. Chloroethyl Chloroformate
98. Chlorofluorocarbons
99. Chloroform
100. Chloroformyl,-4, Morpholine
101. Chloromethane
102. Chloromethyl Ether
103. Chloromethyl Methyl Ether
104. Chloronitrobenzene
105. Chloroprene
106. Chlorosulphonic Acid
107. Chlorotrinitrobenzene
108. Chloroxuron
109. Chromium and Compounds
110. Cobalt and Compounds
111. Copper and Compounds
112. Coumafuryl
113. Comaphos
114. Coumatetralyl
115. Cresols
116. Crimidine
117. Cumene
118. Cyanophos 982 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
119. Cyanothoate
120. Cyanuric Fluoride
121. Cyclohexane
122. Cyclohexanol
123. Cyclohexanone
124. Cycloheximide
125. Cyclopentadiene
126. Cyclopentane
127. Cyclotetamethylenete-tranitramine
128. Cyclotrimethylene Trinitramine
129. DDT
130. Decabromodiphenyl Oxide
131. Demeton
132. Di-Isobutyl Peroxide
133. Di-n-propyl peroxydicarbonate
134. Di-sec-Butyl Peroxydicarbonate
135. Dialifos
136. Diazodinitrophenol
137. Diazomethane
138. Dibenzyl Peroxydicarbonate
139. Dichloroacetylene-o
140. Dichloro obenzene-o
141. Dichlorobenzene-p
142. Dichloroethane
143. Dichloroethyl Ether
144. Dichlorophenol, 2,-4
145. Dichlorophenol,–2, 6
146. Dichlorophenboxy Acetic Acid, -2,4(2,4-D)
147. Dichloropropane,-1,2
148. Dichlorosalicylic Acid, -3,5
149. Dichlorvos (DDVP) 983 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
150. Dicrotophos
151. Dieldrin
152. Diepoxybutane
153. Diethyl Peroxydicarbonate
154. Diethylene Glycol dinitrate
155. Diethylene Triamine
156. Diethyleneglycol Butyl Ether/Diethyleneglycol Butyl Acetate
157. Diethylenetriamine (DETA)
158. Diglycidyl Ether
159. Dithydroperoxypropane, -2, 2
160. Di-isobutyryl peroxide
161. Dimefox
162. Dimethoate
163. Dimethyl Phosphoramidocyanidic Acid
164. Dimthyl Phthalate
165. Dimethylcarbomyl
166. Dimethylnitrosamine
167. Dinitrophenol, Salts
168. Dinitrotoluene
169. Dintro-o-Cresol
170. Dioxane
171. Dioxathion
172. Dioxolane
173. Diphacinone
174. Diphosphoramide Octamethyl
175. Dipropylene Glycolmethylether
176. Disulfoton
177. Endosulfan
178. Endrin
179. Epichlorohydrine
180. EPN 984 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
181. Epoxypropane, 1,-2
182. Ethion
183. Ethyl carbamate
184. Ethyl Ether
185. Ethyl Hexanol, -2
186. Ethyl Mercaptan
187. Ethyl Methacrylate
188. Ethyl Nitrate
189. Ethylamine
190. Ethylene
191. Ethylene Chlorohydrine
192. Ethylene Diamine
193. Ethylene Dibromide
194. Ethylene Dichloride
195. Ethylene Glycol Dinitrate
196. Ethylene Oxide
197. Ethyleneimine
198. Ethylthiocyanate
199. Fensulphothion
200. Fluenetil
201. Fluoro, -4,-2-Hydroxybutyric Acid and Salts Esters, Amides
202. Fluoracetic Acid and salts, Esters, Amides
203. Fluorobutyric Acid, -4, and Salts, Esters, Amides
204. Fluorocortonic Acid, -4, Salts, Esters, Amides
205. Formaldehyde
206. Glyconitrile (Hydroxyacetonitrile)
207. Guanyl, -1,-4- Nitrosaminoguyny1-1 Tetrazene
208. Heptachlor
209. Hexachloro Cyclopentadiene
210. Hexachlorocyclohexane
211. Hexachlorocyclomethane 985 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
212. Hexachlorodibenzo-p-Dioxin, 1, 2, 3, 7, 8, 9
213. Hexafluoropropene
214. Hexamethylphosphoramide
215. Hexamethyl, -3, 3, 6, 9, 9-1, 2, 4, 5-Tetraoxacyclononane
216. Hexamethylenediamine
217. Hexane
218. Hexanitrostilbene, -2,2, 4, 4, 6, 6
219. Hexavalent Chromium
220. Hydrazine
221. Hydrazine Nitrate
222. Hydrochloric Acid
223. Hydrogen
224. Hydrogen Bromide (Hydrobromic Acid)
225. Hydrogen Chloride (Liquified Gas )
226. Hydrogen Cyanide
227. Hydrogen Fluoride
228. Hydrogen Selenide
229. Hydrogen Sulphide
230. Hydroquinone
231. Iodine
232. Isobenzan
233. Isodrin
234. Isophorone Diisocyanate
235. Isopropyl Ether
236. Juglone (5-Hydroxynaphthalene-1, 4-Dione)
237. Lead (inorganic fumes & dusts)
238. Lead 2, 4, 6-Ttrinitroresorcinoxide (Lead Styphnate)
239. Lead Azide
240. Leptophos
241. Lindane
242. Liquefied Petroleum Gas (LPG) 986 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
243. Maleic Anhydride
244. Managanese & Compounds
245. Mercapto Benzothiazole
246. Mercury Alkyl
247. Mercury Fulminate
248. Mercury Methyl
249. Methacrylic Anhydride
250. Methacrylonitrile
251. Methacryloyl Chloride
252. Methamidophos
253. Methanesuphonyl Fluoride
254. Methanthiol
255. Methoxy Ethanol
256. Methoxyethylmercuric Acetate
257. Methyl Acrylate
258. Methyl Alcohol
259. Methyl Amylketone
260. Methyl Bromide (Bromomethane)
261. Methyl Chloride
262. Methyl Chloroform
263. Methyl Cyclohaexene
264. Methyl ethyl Ketone Peroxide
265. Methyl Hydrazine
266. Methyl Isobutyl Ketone
267. Methyl Isobutyl Ketone Peroxide
268. Methyl Isocyanate
269. Methyl Isothiocyanate
270. Methyl Mercaptan
271. Methyl Methacrylate
272. Methyl Parathion
273. Methyl Phoshonic Dichloride 987 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
274. Methyl-N, 2, 4, 6-Tetranitroaniline
275. Methylene Chloride
276. Methylenebis,-4, 4, (2,- chloroaniline)
277. Methyltrichlorosilane
278. Mevinphos
279. Molybdenum & Compounds
280. N-Methyl-N, 2, 4,6- Tetranitroanaline
281. Naptha (Coal Tar)
282. Napthylamine, 2
283. Nickel & Compounds
284. Nickel Tetracarbonyl
285. Nitroaniline-o
286. Nitroaniline-P
287. Nitrobenzene
288. Nitrochlorobenzene-P
289. Nitrocyclohexane
290. Nitroethane
291. Nitrogen Dioxide
292. Nitrogen Oxides
293. Nitrogen Trifluoride
294. Nitroglycerine
295. Nitrophenol-P
296. Nitropropane-1
297. Nitropropane-2
298. Nitrosodimethylamine
299. Nitrotoluene
300. Octabromophenyl Oxide
301. Oleum
302. Oleylamine
303. OO-Diethyl S-Ethysulphonylmethyl
304. OO- Diethyl S-Ethysulphonylmethyl Phosphorothioate 988 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
305. OO- Diethyl S-Ethylthiomethyl Phosphorothioate
306. OO- Diethyl S-Isopropylthiomethyl Phosphorothioate
307. OO- Diethyl S-Propylthiomethyl Phosphorodithioate
308. Oxyamyl
309. Oxydisulfoton
310. Oxygen (liquid)
311. Oxygen Difluoride
312. Ozone
313. Paroxon (diethyl 4-Nitrophenyl Phosphate)
314. Paraquat
315. Parathion
316. Paris green
317. Pentaborane
318. Pentabromodiphenyl Oxide
319. Pentabromophenol
320. Pentachloro Napthalene
321. Pentachloroethane
322. Pentachlorophenol
323. Pentaerythritol Tetranitrate
324. Pentane
325. Pentanone, 2, 4-Methyl
326. Peradetic Acid
327. Perchloroethylene
328. Perchloromethyl Mercaptan
329. Phenol
330. Phenyl Glycidal Ether
331. Phenylene p-Diamine
332. Phenylmercury Acetate
333. Phorate
334. Phosacetim
335. Phosalone 989 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
336. Phosfolan
337. Phosgene (carbonyl chloride)
338. Phosmet
339. Phosphamidon
340. Phosphine (Hydrogen Phosphide)
341. Phosphoric Acid and Esters
342. Phosphoric Acid, Bromoethyl Bromo (2,2-Dimethylpropyl) Bromethyl Ester
343. Phosphoric Acid, Bromoethyl Bromo (2, 2-Dimethylpropyl)
344. Phosphoric Acid, Cloroethyl Bromo (2, 2-Dimethylpropyl Chloroethylester)
345. Phosphorous & Compounds
346. Phostalan
347. Picric Acid, (2, 4, 6-Trinitrophenol)
348. Polybrominated Biphenyls
349. Potassium Arsenite
350. Potassium Chlorate
351. Promurit (1-(3, 4 Dichlorophenyl)-3 Triazenethiocarboxamide)
352. Propanesultone-1, 3
353. Propen-1, -2-Chloro-1, 3-Diol-Diacetate
354. Propylene Oxide
355. Propyleneimine
356. Pyrazoxon
357. Selenium Hexafluoride
358. Semicarbazide Hydrochloride
359. Sodium Arsenite
360. Sodium Azide
361. Sodium Chlorate
362. Sodium Cyanide
363. Sodium Picramate
364. Sodium Selenite
365. Styrene, 1, 1, 3, 2-Tetrachloroethane 990 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
366. Sulfotep
367. Sulphur dichloride
368. Sulphur Dioxide
369. Sulphur Trioxide
370. Sulphuric Acid
371. Sulphoxide, 3-chloropropyloctyl
372. Tellurium
373. Tellurium Hexafluoride
374. Tepp
375. Terbufos
376. Tetrabromobisphenol-A
377. Tetrachloro, 2, 2, 5, 6, 2, 5-Cyclohexadiene-1, 4-Dione
378. Tetrachlorodibenzo-p Dloxin, 2 3, 7, 8(TCDD)
379. Tetraethyl Lead
380. Tetrafluoroethane
381. Tetramethylenedisulphotetramine
382. Tetramethyl Lead
383. Tetranitromethane
384. Thallium & Compounds
385. Thionazin
386. Thinoyl Chloride
387. Tirpate
388. Toluene
389. Toluene-2-4Diisocyanate
390. Toluidine-o
391. Toluene 2, 6-Diisocyanate
392. Trans-1, 4-dichlorobutene
393. Tri-1(cycloexyl) Stannyl-1-H-1, 2, 3-Triazole
394. Triamino, -1, 3 5, 2, 4, 6-Trinitrobenzene
395. Tribromophenol, 2, 4, 6
396. Trichloro Acetyl Chloride 991 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
397. Trichloro Ethane
398. Trichloro Napthalene
399. Trichloro (Chloromethyl) Silane
400. Trichlorodichlorophenylsilane
401. Trichloroethane, 1, 1 –1
402. Trichloroethyl Silane
403. Trichloroethylene
404. Trichloromethanesulphenyl chloride
405. Trichlorophenol, 2, 2, 6
406. Trichlorophenol, 2, 4, 5
407. Triethylamine
408. Triethylenemelamine
409. Trimethyl Chlorosilane
410. Triethylpropane Phosphite
411. Trinitroaniline
412. Trinitroanisole, 2, 2, 4, 6
413. Trinitrobenzene
414. Trinitrobenzoic Acid
415. Trinitrocresol
416. Trinitrophenetole, 2, 5, 6
417. Trinitroresorcinol, 2, 4, 6 ( Styphnic Acid)
418. Trinitrotoluene
419. Triorthocresyl Phosphate
420. Triphenyl Tin Chloride
421. Turpentine
422. Uranium & Compounds
423. Vanadium & Compounds
424. Vinyl Chloride
425. Vinyl Fluoride
426. Vinyl Toluene
427. Warfarin 992 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
428. Xylene
429. Xylidine
430. Zinc & Compounds
431. Zirconium & Compounds 993 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
SCHEDULE -2 [See rules 2(b), 2(e) 2(g)] S.No. Chemicals Threshold Planning Quantities (M.T.)
1 2 3
1. Acrylonitrile 350
2. Ammonia 60
3. Ammonium nitrate (c) 350
4. Ammonium nitrate fertilizers (d) 1,250
5. Chlorine 10
6. Flammable gases as defined in Schedule 1, paragraph (b) (i) 50
7. Highly flammable liquids as defined in Schedule 1, paragraph (b) (ii) 10,000
8. Liquid oxygen 200
9. Sodium chlorate 25
10. Sulphur dioxide 20
11. Sulphur troxide 15
12. Carbonyl chloride 0.750
13. Hydrogen Sulphide 5
14. Hydrogen fluoride 5
15. Hydrogen cyanide 5
16. Carbon disulphide 20
17. Bromine 50
18. Ethylene oxide 5
19. Propylene oxide 5
20. 2-Propenal (Acrolein) 20
21. Bromomethane (Methyl bromide) 20 994 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
22. Methyl isocyanate 0.150
23. Tetraethyl Lead or tetramethyl lead 5
24. 1,2 Dirbromoethane (Ethylene dibromide) 5
25. Hydrogen chloride (liquified gas) .25
26. Diphenyl methane di-isocyanate (MDI) 20
27. Toluene di-isocyanate (TDI) 10 Note : (a) The threshold quantities set out above relate to each installation or group of installations belonging to the same occupier where the distance between installations is not sufficient to avoid, in foreseeable circumstances, any aggravation of major accident hazards. These threshold quantities apply in any case to each group of installations belonging to the same occupier where the between the installations is less than 500 metres.
(b) For the purpose of determining the threshold quantity of a hazardous chemical at an isolated storage, account shall also be taken of any hazardous chemical which is :-
(i) in that part of any pipeline under the control of the occupier having control of the site, which is within 500 metres of that site and connected to it;
(ii)at any other site under the control of the same occupier any part of the boundary of which is within 500 metres of the said site; and
(iii) in any vehicle, vessel, aircraft or hovercraft under the control of the same occupier which is used for storage purpose either at the site or within 500 metres of it;
But no account shall be taken of any hazardous chemical which is in a vehicle, vessel, aircraft or hovercraft used for transporting it.
(c) This applies to ammonium nitrate and mixtures of ammonium nitrate where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight and to aqueous solutions of ammonium nitrate where the concentration of ammonium nitrate is greater than 90 per cent by weight.
(d) This applies to straight ammonium nitrate fertilizers and to compound fertilizers where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight ( a compound fertilizer contains ammonium nitrate together with phosphate and/or potash) 995 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996
SCHEDULE - 3 [see rule 2(b), 2(e), 2(g)] Named Chemicals S.
No.
Chemical Threshold quantity CAS number 1 2 3 4 Group 1-TOXIC CHEMICALS
1. Aldicarb 100 kg 116-06-3
2. 4-Aminodiphenyl 1 kg 96-67-1
3. Amiton 1 kg 78-53-5
4. Anabasine 100 kg 494-52-0
5. Arsenic pentoxide, Arsenic (V) acid and salts 500 kg
6. Arsenic trioxide, Arsenious (III) acid & salts 100 kg
7. Arsine (Arsenic hydride) 10 kg 7784-42-1
8. Azinpho-ethyl 100 kg 2642-71-9
9. Azinpho-methyl 100 kg 86-50-0
10. Benzidine 1 kg 92-87-5
11. Benzidine salts 1 kg -
12. Beryllium (powders & “compounds”) 10 kg -
13. Bis(2-chloroethyl) Sulphide 1 kg 505-60-2
14. Bis (chloromethyl) ether 1 kg 542-88-1
15. Carbofuran 100 kg 1563-66-2
16. Carbophenothion 100 kg 786-19-6
17. Chlorfenvinphos 100 kg 470-90-6
18. 4-(Chloroformyl) morpholine 1 kg 15159-40-7
19. Chloromethyl methyl ether 1 kg 107-30-2
20. Cobalt (metal, oxides, carbonates, sulphides, as powders) 1000 kg - 996 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996 S.
No.
Chemical Threshold quantity CAS number 1 2 3 4
21. Crimidine 100 kg 535-89-7
22. Cyanothoate 100 kg 3734-90-0
23. Cycloheximide 100 kg 66-81-9
24. Demeton 100 kg 8065-48-3
25. Dialifos 100 kg 10311-84-9
26. OO-Diethyl S-ethylsuphinylmethyl phosphorothioate 100 kg 2588-06-8
27. OO-Diethyl S-ethylsuphonylmethyl phosphorothioate 100 kg 2588-06-9
28. OO-Diethyl S-ethylthiomethyl phosphorothioate 100 kg 2600-69-3
29. OO-Diethyl S-isopropylthiomethyl phosphorodithioate 100 kg -
30. OO-Diethyl S- propylthiomethyl phosphorodithioate 100 kg 3309-68-0
31. Dimefox 100 kg 115-26-4
32. Dimethylcarbamoyl chloride 1 kg 79-44-7
33. Dimethylnitrosamine 1 kg 62-75-9
34. Dimethyl phospho amidocyanidic acid 1000 kg 7781-6
35. Diphacinone 100 kg 82-66-6
36. Disulfoton 100 kg 298-04-4
37. EPN 100 kg 2104-64-5
38. Ethion 100 kg 563-12-2
39. Fensulfothin 100 kg 115-90-2
40. Fluenetil 100 kg 4301-50-2
41. Fluoroacetic acid, 1 kg 144-49-0
42. Fluoroacetic acid, salts 1 kg
43. Fluoroacetic acid, esters 1 kg
44. Fluoroacetic acid, amides 1 kg
45. 4-Fluorobutyric acid 1 kg
46. S-Fluorobutyric acid, salts 1 kg 997 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996 S.
No.
Chemical Threshold quantity CAS number 1 2 3 4
47. 4- Fluorobutyric acid, esters 1 kg
48. 4- Fluorobutyric acid 1 kg
49. 4- Fluorocrotonic acid, 1 kg 37759-72-1
50. 4- Fluorocrotonic acid, salts 1 kg
51. 4- Fluorocrotonic acid, esters 1 kg
52. 4- Fluorocrotonic acid, amides 1 kg
53. 4-Fluoro-2-hydroxybutyric acid 1 kg
54. 4-Fluoro-2-hydroxy butyric acid, salts 1 kg
55. 4-Fluoro-2-hydroxybutyric acid, esters 1 kg
56. 4-Fluoro 2-hyrdoxybutyric acid, amides 1 kg
57. Glyconitrile (Hydroxyacetonitrile) 100 kg 107-16-4
58. 1, 2, 3, 7, 8, 9,-Hexachlorodibenzo-p-dioxine 100 kg 19408-74-3
59. Hexamethylphophoramide 1 kg 680-31-9
60. Hydrogen selenide 10 kg 7783-07-5
61. Isobenzan 100 kg 297-78-9
62. Isodrin 100 kg 465-73-6
63. Juglone (5-Hydroxynaphthalene) 1, 4-dioone) 100 kg 481-39-0
64. 4, 4-Methylenebis (2-chloroaniline) 10 kg 101-14-4
65. Methyl isocyanate 150 kg 624-83-9
66. Mevinphos 100 kg 7786-34-7
67. 2-Napthylamine 1 kg 91-59-8
68. Nickel (metal oxides, carbonates , sulphide, as powders) 1000 kg -
69. Nickel tetracarbonyl 10 kg 13463-39-3
70. Oxydisulfoton 100 kg 2497-07-6
71. Oxygen difluoride 10 kg 7783-41-7
72. Paraoxan (Deithyl 4-nitrophenyl phosphate) 100 kg 311-45-5
73. Parathion 100 kg 56-38-2 998 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996 S.
No.
Chemical Threshold quantity CAS number 1 2 3 4
74. Parathion-methyl 100 kg 298-00-0
75. Pentaborane 100 kg 19624-22-7
76. Phorate 100 kg 298-02-2
77. Phosazetim 100 kg 4104-14-7
78. Phosgene (carbonul chloride) 750 kg 75-55-5
79. Phoshamidon 100 kg 13171-21-6
80. Phosphine (Hydrogen phosphide) 100 kg 5836-73-7
81. Promurit ( 1-(3, 4-Dichlorophenyl)-3 triazenethiocarboxamide 100 kg 5836-73-7
82. 1, 3-Propanesultone 1 kg 1120-71-4
83. 1-Propene-2-chloro-1, 3-diol diacetate 10 kg 10118-72-6
84. Pyrazoxom 100 kg 108-34-9
85. Selenium hexafluoride 10 kg 7783-79-1
86. Sodium selenite 100 kg 10102-18-8
87. Stibine (Antimony hydride) 100 kg 7803-52-3
88. Sulfotep 100 kg 3689-24-5
89. Sulphur dichloride 1000 kg 10545-99-0
90. Tellurium hexafluoride 100 kg 7783-80-4
91. TEPP (Tetraethyl pyrophosphate) 100 kg 107-49-3
92. 2, 3, 7, 8-Tetrachlorodibenzo-p-dioxine (TCDD) 1 kg 1746-01-6
93. Tetramethylenedisulphotetramine 1 kg 80-12-6
94. Thionazine 100 kg 297-97-2
95. Tirpate (2, 4-Dimethyl-1, 3-dithiolane- 2carboxaldehyde O-methylcarbarnoyloxime) 100 kg 26419-73-8
96. Trichloromethanesulphenyl chloride 100 kg 594-42-3
97. 1-Tri ( cyclohexyl)v stannyl IIH-1, 2, 3-triazole 100 kg 40183-11-8
98. Triethylenemelamine 10 kg 51-18-3
99. Warfarin 100 kg 81-81-2 999 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996 S.
No.
Chemical Threshold quantity CAS number 1 2 3 4 GROUP 2- TOXIC CHEMICALS
100. Acetone cycanohydrin (2-Cyanopropan-2-1) 200 T 75-86-5
101. Acrolein (2-Propenal) 20 T 107-02-8
102. Acrylonitrile 20 T 107-13-1
103. Allylalcohol (Propen-1-01) 200 T 107-18-6
104. Allamine 200 T 107-11-9
105. Ammonia 50 T 7664-41-7
106. Bromine 40 T 7726-95-6 10 7. Carbon disulphide 20 T 75-15-0
108. Chlorine 10 T 7782-50-5
109. Diphenyl methane di-isocyanate (MDI) 20 T 101-68-8
110. Ethylene dibormide (1,2-Dibormoethane) 5 T 106-93-4
111. Ethyleneimine 50 T 151-56-4
112. Formaldehyde (Concentration >90%) 5 T 50-00-0
113. Hydrogen chloride (liquified gas) 25 T 7647-01-0
114. Hydrogen cyanide 5 T 74-90-8
115. Hydrogen fluoride 5 T 7664-39-3
116. Hydrogen sulphide 5 T 7783-06-4
117. Methyl bromide ( bromomethane) 20 T 74-83-9
118. Nitrogen oxides 50 T 11104-93-1
119. Propyleneimine 50 T 75-55-8
120. Sulphur dioxide 20 T 7446-09-5
121. Sulphur trioxide 15 T 7446-11-9
122. Tetraethyl lead 5 T 78-00-2
123. Tetramethyl lead 5 T 75-74-1
124. Toluene 2, 4, di-isocyanate (TDI) 10 T 584-84-9 1000 The Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996 S.
No.
Chemical Threshold quantity CAS number 1 2 3 4 GROUP 3- HIGHLY REACTIVE CHEMICALS
125. Acetylene (ethyne) 5 T 74-86-2
126. 1. Ammonium nitrate (c) II. Ammonium nitrate in the form of fertilisers(d) 350 T 250 T 6484-52-2
127. 2,2-Bis (tert-butylperoxy) butane (concentration >70%) 5 T 2167-23-9
128. 1,1-Bis (tert-butylperoxy) cyclohexane (concentration –80%) 5 T 3006-86-8
129. tert-Butyl peroxyacetate (concentation –70%) 5 T 107-71-1