(1) This rule shall apply to an 1[industrial activity or isolated storage] in which a hazardous chemical, which satisfies any of the criteria laid down in 2[Part I of Schedule 1 or] is listed in Column (2) in Part II of that Schedule, is or may be involved.
3[(2) An occupier of an industrial activity or isolated storage in terms of sub-rule (1) shall arrange to obtain or develop information in the form of Safety Date Sheet as specified I Schedule 5. The information shall be made accessible to workers upon request for reference.]
(3) The Occupier while obtaining or developing a 4[safety data sheet as specified in Schedule 5] in respect of a hazardous chemical handled by him shall ensure that the information is recorded accurately and reflects the scientific evidence used in making the hazard determination. In case, any significant information regarding hazard of a chemical is available, it shall be added to the 4[safety data sheet as specified in Schedule 5] as soon as practicable:
(4) Every container of a hazardous chemical shall be clearly labeled or marked to identify, -
(a) the contents of the container ;
(b) the name and address of the manufacturer or importer of the hazardous chemical; and
(c) the physical, chemical and toxicological data of the hazardous chemical.
(5) In case where it is impracticable to label a chemical in view of the size of the container or the nature of the package, provision should be made for other effective means like tagging or accompanying documents.
________________________________________________________________________________________________________ 1 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for “ industrial activity “.
2 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for “ Part I of Schedule I and “.
3 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
4 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for “ material safety data sheet ”.
5 3[3-A. Duties of Inspector. – The Inspector shall –
(a) inspect the industrial activity or isolated storage atleast once in a calendar Year ;
(b) send a status report annually on the compliance with these Rules by the occupiers to the ministry of Environment and Forests through the Directorate General Factory Advice Service and Labour Institutes and Ministry of Labour, Government of India ; and
(c) enforce direction and procedures in respect of industrial activities or isolated storage covered under the Act, and in respect of pipelines upto the distance of 500 metres from the outside of the perimeter of the factory, regarding ----
(i) notification of the major accidents as per sub – rules (1) and (2) of rules 5 ;
(ii) notification of sites as per rules 7 and safety reports and (Sic.) 8 ;
(iii) safety audits as per rules 10 to 12 ;
(iv) preparation of on-site emergency plans as per rule 13 and involvement in the preparation of off- site emergency plans as per rules 13 in consultation with District Collector or District Emergency Authority. ]
4. General responsibility of the occupier.----- (1) This rule shall apply to, ------- 1[(a) an industrial activity, in which a hazardous chemical, which satisfies any of the criteria laid down in part I of Schedule 1 2[or listed] in Column 2 in Part II of the said Schedule is or may be involved. ] 3[ (b) isolated storage of a hazardous chemical listed in Schedule 2 in a quantity equal to or more than the threshold quantity specified in column (3), thereof.]
______________________________________________________________________________ 1 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
2 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018.
3 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018.
6
(2) 1[ An Occupier in terms of sub- rule (1) above shall provide information on demand to show that he has] ------
(a) identified the major accident hazards; and
(b) taken adequate steps to -----
(i) prevent such major accidents and to limit their consequences to persons and the environment ; and
(ii) provide the persons working on the site with the information, training and equipment including antidotes necessary to ensure their 2[ safety and health].
5. Notification of major accidents.----- (1) Where a major accident occurs on a 3[ site or in a pipeline], 4[ the occupier shall within 48 hours] notify the Inspector and the Chief Inspector of that Accident, and furnish thereafter to the 5[ Inspector and Chief Inspector a repot] relating to the accident in installments, if necessary, in Schedule 6.
6[(2) The Inspector and Chief Inspector shall, on receipt of the report in accordance with in sub –rule (1) undertake a full analysis of the major accident and send the requisite information to the Ministry of Environment and Forests through the Directorate General Factory Advice and Service and Labour Institutes and Ministry of Labour, Government of India.]
7[(3) An occupier shall notify to the Inspector about the steps taken to avoid any repetition of such occurrence in the factory.
(4) The Inspector and Chief Inspector shall compile information regarding major accidents and make available a copy of the same to the Ministry of Environment and Forests through the Directorate General Factory Advice and Service and Labour Institutes and Ministry of Labour, Government of India.
(5) The Inspector and Chief Inspector shall inform the occupier in writing of any lacuna which in their opinion needs to be rectified to avoid major accidents. ] ____________________________________________________________________________ 1 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for the expression commencing with the words “ An occupier ” and ending with the words “ to show that he has “.
2 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for “ safety ” .
3 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for “ site ” .
4 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for the words “ the occupier shall forthwith ”.
5 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008) for the words “Chief Inspector a repot”.
6 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
7 Sub – Rules (3) to (5), added by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
7
6. 1[Industrial activities or isolated storage to which rules 7 to 15 apply. ]---------
(1) (a) 2[ Rules 7, 8, 13 and 15] shall apply to an industrial activity, other than isolated storage, in which there is involved a 3[ threshold quantity] of a hazardous chemical listed in column (2) in the Table in Schedule 3 which is equal to or more than the 3[ threshold quantity] specified in column (3) of that Schedule in respect of that chemical.
(b) Rules 10 to 12 shall apply to an industrial activity, other than isolated storage, in which there is involved a 3[threshold quantity] of a hazardous chemical listed in column (2) in the Table in Schedule 3 which is equal to or more than the 3[threshold quantity] specified in column (4) in respect of that chemical.
(c) 4[ Rules 7 and 8] shall apply to an isolated storage, in which there is involved a 3[threshold quantity] of a hazardous chemical listed in column (2) in the Table in Schedule 2 which is equal to or more than the 3[ threshold quantity] specified in column (3) of that Schedule in respect of that chemical ; and
(d) 5[ Rules 10 to 13 and 15] shall apply to an isolated storage, in which there is involved a 3[ threshold quantity] of a hazardous chemical listed in column (2) in the Table in Schedule 2 which is equal to or more than the 3[ threshold quantity] specified in column (4) of that Schedule in respect of that chemical.
6[ (2) ****] ____________________________________________________________________________________________ 1 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for the heading “ Industrial activities to which rules 7 to 15 apply ” .
2 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for “ Rules 7 to 9 and 13 to 15 ” .
3 Subs. by G.O. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for the expression “ quantity ”.
4 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008), for the expression “ Rules 7 to 9”.
5 Subs. for “Rule 10 to 15 “ by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
6 Sub –Rule (2), omitted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
8
7. 1[ Approval and Notification of sites. ] ----- (1) An occupier shall not undertake any 2[industrial activity or isolated storage] unless he has submitted a written report to the Chief Inspector containing the particulars specified in Schedule 7, atleast 3[90 days] before commencing that activity or before such shorter time as the Chief Inspector may specify and for the purposes of this sub –rule, an activity in which subsequently there is or is liable to be a 4[threshold quantity] specified in column (3) in the Table in Schedule 2 and 3 or more of an additional hazardous chemical shall be deemed to be a different activity and shall be notified accordingly.
5[(2) The Chief Inspector, within 60 days from the date of receipt of the report in accordance with sub- rule (1) of this rule shall examine and on examination of the report if he is of the opinion that contravention of the provision of the Act or the Rules has taken place, he may issue notice for obtaining compliance.]
8. 6[Updating of the Site Notification ] ----- Where an activity has been reported in accordance with sub –rule (1) of rule 7 and the occupier makes a change in it (including an increase or decrease in the maximum quantity of a hazardous chemical to which this rule applies, which is, or is liable to be, at the site or in the 7[ pipeline or at the cessation ] of the activity) which affects the particulars specified in that report or any subsequent report made under this Rule, the Occupier shall forthwith furnish a further report to the 8[Inspector and the Chief Inspector].
______________________________________________________________________________ 1 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018 for the expression “Notification of Sites”.
2 Subs. for “Industrial activities” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
3 Subs. For “3 Months”, by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
4 Subs. for “quantity” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
5 Sub –Rule (2), submitted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
6 Subs. for the heading “Updating notification under rule 7” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
7 Subs. for “pipeline or the cessation” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
8 Subs. for “Chief Inspector ” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
9 1[ 9. Transitional Provision. ----- **** ]
10. 2[ Safety Reports and Safety Audit Reports]. ------- (1) Subject to sub-rules (2) and
(3), an Occupier shall not 3[undertake any industrial activity or isolated storage] to which this rule applies, unless he has prepared a safety report on that industrial activity containing the information specified in Schedule 8 and has sent a copy of that report to the Chief Inspector atleast 4[ninety days] before commencing that activity.
5[(2) The occupiers of both the new and the existing industrial activity or isolated storages shall arrange to carry out safety audit by a competent agency to be accredited by an Accreditation Board of Safety Auditors or recognizes for the purposes as competent in the opinion of the Chief Inspector and such safety auditing shall be carried out as follows : ------
(a) Internally, once in a year by a team of suitable plant personnel :
Provided that the year in which an external audit is carried out, internal audit need not be carried out for that year.
(b) Externally, once in two years by a competent agency accredited in this behalf.
(3) The occupier within 30 days of the completion of the safety audit, shall send a report to the Chief Inspector with respect to the implementation of the audit recommendations.]
______________________________________________________________________________ 1 Rule 9 omitted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
2 Subs. for the heading “Safety Reports ” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
3 Subs. for the words “under take any industrial activity ” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
4 Subs. for “3 months” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
5 Sub- Rules (2) and (3), substituted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
10
11. 1[Updating of safety reports under rule 10]. ----- (1) Where an occupier has made a safety report in accordance with sub-rule (1) of rule 10, he shall not make any modification to the 2[industrial activity or isolated storage] to which that safety report relates which could materially affect the particulars in that report, unless he has made a further report to take account of these modifications and has sent a copy of that report to the 3[Inspector and the Chief Inspector atleast 90 days] before making those modifications.
(2) Where an occupier has made a report in accordance with rule 10 and sub-rule (1) above and that 2[industrial activity or the isolated storage] is continuing the occupier shall within three years from the date of the last such report, make a further report which shall have regard in particular to new technical knowledge which has affected particulars in the previous report relating to safety and hazard assessment, and shall within 4[30 days] or such longer time as the 5[Inspector and the Chief Inspector ] may specify in writing, send a copy of the report to the 5[Inspector and the Chief Inspector].
6[12.Requirement for further information to be sent to the Inspector or the Chief Inspector.--- Where in accordance with rules 10 and 11, an occupier has sent safety report and safety audit report relating to an industrial activity or isolated storage to the Inspector or the Chief Inspector, the Inspector or the Chief Inspector, may, by a notice served on the occupier require him to provide such additional information as may be specified in the notice and the occupier shall sent that information to the Inspector or Chief Inspector within 90 days.]
______________________________________________________________________________ 1 Subs. for the heading “Updating of reports under rule 10” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
2 Subs. for the words “industrial activity ” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
3 Subs. for “Chief Inspector atleast 3 months” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
4 Subs. for “one month “, by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
5 Subs. for the words “Chief Inspector” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
6 Rule 12 substituted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
11
13. Preparation of on–site emergency plans by the occupier ------ 1[(1) The occupier shall prepare, keep up-to-date and furnish to the Inspector or Chief Inspector an on-site emergency plan containing details specified in Schedule 9 and detailing how major accidents will be dealt with on the site on which the industrial activity or isolated storage is carried on and that plan shall include the name of the person who is responsible for safety on the site and the names of those who are authorized to take action in accordance with the plan in case of an emergency.]
(2) The occupier shall ensure that the emergency plan prepared in accordance with sub-rule (1) takes into account any modification made in the 2[industrial activity or isolated storage] and that every person on the site who is 3[concerned with] the plan is formed of the relevant provisions.
(3) The occupier shall prepare emergency plan required under sub-rule (1) ------- 4[(a) before the commencement of industrial activity or isolated storage:
(b) within 90 days of coming into operation of these Rules in case of an existing industrial activity or isolated storage.]
5[(4) The occupier shall ensure that a mock drill of the on-site emergency is conducted atleast once in every six months.
(5) A detailed report of a mock drill conducted under sub-rule (4) shall be made immediately available to the Inspector or the Chief Inspector.]
6[14. Preparation of off-site emergency plans. -------**** ] 1 Sub-Rule (1) substituted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
2 Subs. for the words “industrial activity ” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
3 Subs. for the words “affected by ” by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
4 Clauses (a) and (b), substituted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
5 Sub-Rules (4) and (5) added by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
6 Rule 14 omitted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
12 1[15. Information to be given to persons liable to be affected by a major accident.----- (1) The occupier shall take appropriate steps to inform persons outside the site who are likely to be in an area which may be affected by a major accident about ------
(a) the nature of the major accident hazard ; and
(b) the safety measures and the ‘Do’s ‘ and ‘Don’ts ‘ which should be adopted in the event of a major accident.
(2) The occupier shall take the steps required under sub-rule (1) to inform persons about and industrial activity or isolated storage before that activity is commenced, except that in respect of an existing industrial activity or isolated storage, the occupier shall comply with the requirements of sub-rule (1) within 90 days of coming into operation of these Rules.]
2[16. Disclosure of information.------- Where for the purpose of evaluating information notified under Rules 5,7 to 15, the Inspector or the Chief Inspector discloses that information to some other person, that other person shall not use that information, for any purpose except for a purpose of the Inspector or the Chief Inspector disclosing it, as the case may be, and before disclosing that information, the Inspector or the Chief Inspector, as the case may be, shall inform that other person of this obligations under this rule.]
3[17. Improvement notice.----- ***]
18. Power to amend Schedules.------- The State government may, at any time, by notification amend the Schedules.
______________________________________________________________________________ 1 Rule 15, substituted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
2 Rule 16, substituted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
3 Rule 17 omitted by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
13 1[SCHEDULE 1 [See rule 2(a) (i), 3 (1), 4(1) (a) and 4 (2)] [Part -I]
(a) Toxic Chemicals: Chemicals having the following values of acute toxicity and which owing to their physical and chemical properties are capable of producing major accident hazards:
S.No.
(1) Toxicity
(2) Oral toxicity LD 50(mg/kg)
(3) Dermal toxicity LD 50 (mg/kg)
(4) Inhalation toxicity LC 50(mg/liter)
(5)
1. Extremely toxic >5 <40 <0.5
2. Highly toxic >5-50 >40-200 <0.5-2.0
3. Toxic >50-200 >200-1000 >2-10
(b) Flammable Chemicals:
(1) flammable gases: Gases which at 20oC and at standard pressure of 101.3KPa are :-
(i) ignitable when in a mixture of 13 percent or less by volume with air ;or
(ii) have a flammable range with air of at least 12 percentage points regardless of the lower flammable limits.
Note: The flammability shall be determined by tests or by calculation in accordance with methods adopted by International Standards Organization ISO Number 10156 of 1990 or by Bureau of Indian Standard ISI Number 1446 of 1985.
(2) Extremely flammable liquids: chemicals which have flash point lower than or equal to 23oC and boiling point less than 35oC.
(3) Very highly flammable liquids: chemicals which have a flash point lower than or equal to 23oC and initial boiling point higher than 35oC.
1 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018.
14
(4) Highly inflammable liquids: chemicals which have a flash point lower than or equal to 60oC but higher than 23oC.
(5) Flammable liquids: chemicals which have a flash point higher than 60oC but lower than
90oC.
(C) Explosives: Explosives means a solid or liquid or pyrotechnic substance (or a mixture of substances) or an article -
(i) which is in itself capable by chemical reaction of producing gas at such a temperature and pressure and at such a speed as to cause damage to the surroundings ;
(ii) which is designed to produce an effect by heat, light, sound, gas or smoke or a combination of these as the result of non-detonative, self-sustaining exothermic reaction. ] 15 1[Part – II Sl. No. List of Hazardous Chemicals
(1) ( 2)
1. Acetaldehyde
2. Acetic acid
3. Acetic anhydride
4. Acetone
5. Acetone cyanohydrin
6. Acetone thiosemicarbazide
7. Acetonitrile
8. Acetylene
9. Acetylene tetra chloride
10. Acrolein
11. Acrylamide
12. Acrylonitrile
13. Adiponitrile
14. Aldicarb
15. Aldrin
16. Allyl Alcohol
17. Allyl amine
18. Allyl chloride
19. Aluminium (powder)
20. Aluminium azide
21. Aluminium borohydride
22. Aluminium chloride
23. Aluminium fluoride
24. Aluminium phosphide
25. Amino diphenyl
26. Amino pyridine
27. Aminophenol-2
28. Aminopterin
29. Amiton
30. Amiton dialate
31. Ammonia
32. Ammonium Chloro platinate
33. Ammonium nitrate
34. Ammonium nitrite 16
35. Ammonium picrate
36. Anabasine
37. Aniline
38. Aniline 2,4,6-trimethyl
39. Anthraquinone
40. Antimony pentafluoride
41. Antimycin A
42. ANTU
43. Arsenic pentoxide
44. Arsenic trioxide
45. Arsenic trichloride
46. Arsine
47. Asphalt
48. Azinphos-ethyl
49. Azinphos-methyl
50. Bacitracin
51. Barium azide
52. Barium nitrate
53. Barium nitride
54. Benzal chloride
55. Benzenamine, 3-trifluoromethyl
56. Benzene
57. Benzene sulfonyl chloride
58. Benzene, 1-(chloromethyl) -4 Nitro
59. Benzene arsenic acid
60. Benzidine
61. Benzidine Salts
62. Benzimidazole, 4,5-Dichloro-2 (Trifluoromethyl)
63. Benzoquinone-P
64. Benzotrichloride
65. Benzoyl chloride
66. Benzoyl peroxide
67. Benzyl chloride
68. Beryllium (powder)
69. Bicyclo (2,2,1) Heptane-2-carbonitrile
70. Biphenyl
71. Bis (2-Chloroethyl) sulphide
72. Bis (Chloromethyl) ketone
73. Bis (Tert-butylperoxy) cyclo hexane 17
74. Bis(Tert-butyl peroxy)butane
75. Bis(2,4,6-Trimitrophenylamine)
76. Bis (Chloromethyl)Ether
77. Bismuth and compounds
78. Bisphenol-A
79. Bitoscanate
80. Boron Powder
81. Boron trichloride
82. Boron trifluoride
83. Boron trifluoride comp. With methylether, 1:1
84. Bromine
85. Bromine pentaflouride
86. Bromo chloro methane
87. Bromodialone
88. Butadiene
89. Butane
90. Butanone-2
91. Butyl amine tert
92. Butyl glycidal ether
93. Butyl isovalerate
94. Butyl peroxymaleate tert
95. Butyl vinyl ether
96. Butyl-n-mercaptan
97. C.I.Basic green
98. Cadmium oxide
99. Cadmium stearate
100. Calcium arsenate
101. Calcium carbide
102. Calcium cyanide
103. Camphechlor (Toxaphene)
104. Cantharidin
105. Captan
106. Carbachol chloride
107. Carbaryl
108. Carbofuran (Furadan)
109. Carbon tetrachloride
110. Carbon disulphide
111. Carbon monoxide
112. Carbophenothion 18
113. Carvone
114. Cellulose nitrate
115. Chloroacetic acid
116. Chlordane
117. Chlorofenvinphos
118. Chlorinated benzene
119. Chlorine
120. Chlorine oxide
121. Chlorine trifluoride
122. Chlormephos
123. Chlormequat chloride
124. Chloroacetal chloride
125. Chloroacetaldehyde
126. Chloroaniline -2
127. Chloroaniline -4
128. Chlorobenzene
129. Chloroethyl chloroformate
130. Chloroform
131. Chloroformyl morpholine
132. Chloromethane
133. Chloromethyl methyl ether
134. Chloronitrobenzene
135. Chlorophacinone
136. Chlorosulphonic acid
137. Chlorothiophos
138. Chloroxuron
139. Chromic acid
140. Chromic chloride
141. Chromium powder
142. Cobalt carbonyl
143. Cobalt Nitrilmethylidyne compound
144. Cobalt ( powder)
145. Colchicine
146. Copper and compounds
147. Copper oxychloride
148. Coumafuryl
149. Coumaphos
150. Coumatetralyl
151. Crimidine 19
152. Crotenaldehyde
153. Crotonaldehyde
154. Cumene
155. Cyanogen bromide
156. Cyanogen iodide
157. Cyanophos
158. Cyanothoate
159. Cyanuric fluoride
160. Cyclo hexylamine
161. Cyclohexane
162. Cyclohexanone
163. Cycloheximide
164. cyclopentadiene
165. Cyclopentane
166. Cyclotetramethylenetetranitramine
167. Cyclotrimethylenetrinitramine
168. Cypermethrin
169. DDT
170. Decaborane (1:4)
171. Demeton
172. Demeton S-Methyl
173. Di-n-propyl peroxydicarbonate ( Conc=80%)
174. Dialifos
175. Diazodinitrophenol
176. Dibenzyl peroxydicarbonate ( Conc > =90%)
177. Diborane
178. Dichloroacetylene
179. Dichlorobenzalkonium chloride
180. Dichloroethyl ether
181. Dichloromethyl phenylsilane
182. Dichlorophenol-2,6
183. Dichlorophenol-2,4
184. Dichlorophenoxy acetic acid
185. Dichloropropane-2,2
186. Dichlorosalicylic acid-3,5
187. Dichlorovos (DDVP)
188. Dicrotophos
189. Dieldrin
190. Diepoxy butane http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/167.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/180.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/182.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/185.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/186.pdf 20
191. Diethyl carbamazine citrate
192. Diethyl chlorophosphate
193. Diethyl ethanolamine
194. Diethyl peroxydicarbonate (Conc=30%)
195. Diethyl phenylene diamine
196. Diethylamine
197. Diethylene glycol
198. Diethylene glycol dinitrate
199. Diethylene triamine
200. Diethyleneglycol butyl ether
201. Diglycidyl ether
202. Digitoxin
203. Dihydroperoxypropane (Conc>= 30%)
204. Diisobutyl peroxide
205. Dimefox
206. Dimethoate
207. Dimethyl dichlorosilane
208. Dimethyl hydrazine
209. Dimethyl nitrosoamine
210. Dimethyl phenylene diamine
211. Dimethyl phosphoramidicyanidic acid (TABUM)
212. Dimethyl phosphorochloridothioate
213. Dimethyl sulfolane (DMS)
214. Dimethyl sulphide
215. Dimethylamine
216. Dimethylaniline
217. Dimethyl carbonyl chloride
218. Dimetilan
219. Dinitro-o-cresol
220. Dinitrophenol
221. Dinitrotoluene
222. Dinoseb
223. Dinoterb
224. Dioxane-P
225. Dioxathion
226. Dioxine N
227. Diphacinone
228. Diphosphoramide octamethyl
229. Diphenyl methane di-isocynate (MDI) http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/192.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/200.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/203.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/204.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/213.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/215.pdf 21
230. Dipropylene Glycol Butyl ether
231. Dipropylene glycolmethylether
232. Disec-butyl peroxydicarbonite (Conc>80%)
233. Disulfoton
234. Dithiazamine iodide
235. Dithiobiurate
236. Endosulfan
237. Endothion
238. Endrin
239. Epichlorohydrine
240. EPN
241. Ergocalciferol
242. Ergotamine tartarate
243. Ethanesulfenyl chloride, 2 chloro
244. Ethanol 1-2 dichloracetate
245. Ethion
246. Ethoprophos
247. Ethyl acetate
248. Ethyl alcohol
249. Ethyl benzene
250. Ethyl bis amine
251. Ethyl bromide
252. Ethyl carbamate
253. Ethyl ether
254. Ethyl hexanol-2
255. Ethyl mercaptan
256. Ethyl mercuric phosphate
257. Ethyl methacrylate
258. Ethyl nitrate
259. Ethyl thiocyanate
260. Ethylamine
261. Ethylene
262. Ethylene chlorohydrine
263. Ethylene dibromide
264. Ethylene diamine
265. Ethylene diamine hydrochloride
266. Ethylene flourohydrine
267. Ethylene glycol
268. Ethylene glycol dinitrate http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/233.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/239.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/243.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/259.pdf 22
269. Ethylene oxide
270. Ethylenimine
271. Ethylene dichloride
272. Femamiphos
273. Femitrothion
274. Fensulphothion
275. Fluemetil
276. Fluorine
277. Fluoro 2-hydroxy butyric acid, amid salt ester
278. Fluoroacetamide
279. Fluoroacetic acid amide salts esters
280. Fluoroacetyl chloride
281. Fluorobutyric acid amide salt esters
282. Fluorocrotonic acid amides salts esters
283. Fluorouracil
284. Fonofos
285. Formaldehyde
286. Formetanate hydrochloride
287. Formic acid
288. Formoparanate
289. Formothion
290. Fosthiotan
291. Fuberidazole
292. Furan
293. Gallium Trichloride
294. Glyconitrile (Hydroxyacetonitrile)
295. Guanyl-4-nitrosaminoguynyl-1-tetrazene
296. Heptachlor
297. Hexamethyl - tetra –oxyacyclononate (Conc 75%)
298. Hexachlorobenzene
299. Hexachlorocyclohexane (Lindane)
300. Hexachlorocyclopentadiene
301. Hexachlorodibenzo-p-dioxin
302. Hexachloronapthalene
303. Hexafluoropropanone sesquihydrate
304. Hexamethyl phosphoramide
305. Hexamethylene diamine NN dibutyl
306. Hexane http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/276.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/278.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/280.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/283.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/295.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/303.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/305.pdf 23
307. Hexanitrostilbene 2 2 4 4 6 6
308. Hexene
309. Hydrogen selenide
310. Hydrogen sulphide
311. Hydrazine
312. Hydrazine nitrate
313. Hydrochloric acid(Gas)
314. Hydrogen
315. Hydrogen bromide
316. Hydrogen cyanide
317. Hydrogen fluoride
318. Hydrogen peroxide
319. Hydroquinone
320. Indene
321. Indium powder
322. Indomethacin
323. Iodine
324. Iridium tetrachloride
325. Ironpentacarbonyl
326. Iso benzan
327. Isoamyl alcohol
328. Isobutyl alcohol
329. Isobutyro nitrile
330. Isocyanic acid 3,4-dichlorophenyl ester
331. Isodrin
332. Isofluorophosphate
333. Isophorone diisocyanate
334. Isopropyl alcohol
335. Isopropyl chlorocarbonate
336. Isopropyl formate
337. Isopropyl methyl pyrazolyl dimethyl carbamate