butene
631. Tri nitro anisole
632. Tri (Cyclohexyl) methylstannyl 1,2,4 triazole
633. Tri (Cyclohexyl) stannyl-1H-1, 2, 3-triazole
634. Triaminotrinitrobenzene
635. Triamphos
636. Triazophos
637. Tribromophenol 2, 4, 6
638. Trichloro napthalene
639. Trichloro chloromethyl silane
640. Trichloroacetyl chloride
641. Trichlorodichlorophenylsilane
642. Trichloroethyl silane
643. Trichloroethylene
644. Trichloromethane sulphenyl chloride
645. Trichloronate
646. Trichlorophenol 2, 3, 6
647. Trichlorophenol 2, 4, 5
648. Trichlorophenyl silane
649. Tricholorophon
650. Triethoxy silane
651. Triethylamine
652. Triethylene melamine
653. Trimethyl chlorosilane
654. Trimethyl propane phosphite
655. Trimethyl tin chloride http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/629.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/630.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/649.pdf 32
656. Trinitro aniline
657. Trinitro benzene
658. Trinitro benzoic acid
659. Trinitrophenetole
660. Trinitro-m-cresol
661. Trinitro toluene
662. Triorthocresyl phosphate
663. Triphenyl tin chloride
664. Tris (2-chloroethyl)amine
665. Turpentine
666. Uranium and its compounds
667. Valinomycin
668. Vanadium pentoxide
669. Vinyl acetate monomer
670. Vinyl bromide
671. Vinyl chloride
672. Vinyl cyclohexane dioxide
673. Vinyl fluoride
674. Vinyl norbornene
675. Vinyl toluene
676. Vinyledene chloride
677. Warfarin
678. Warfarin sodium
679. Xylene dichloride
680. Xylidine
681. Zinc dichloropentanitrile
682. Zinc phosphide
683. Zirconium and compounds ] ______________________________________________________________________________ 1 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018.
http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/663.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/664.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/668.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/669.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/670.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/674.pdf http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/682.pdf 33
SCHEDULE 2 [See rule 2 (c), 4(1)(b), 6 (1) (c) and (d)] ISOLATED STORAGE OF INSTALLATION OTHER THAN THOSE COVERED BY SCHEDULE 4
(a) The threshold quantities set out below relate to each installation or group of installations belonging to the same occupier where the distance between installations is not sufficient to avoid, in foreseeable circumstances, any aggravation of major accident hazards.
These threshold quantities apply in any case to each group of installations belonging to the same occupier where the distance between the installations is less than 500 metres.
(b) For the purpose of determining the threshold quantity of hazardous chemical at an isolated storage, account shall also be taken of any hazardous chemical, which is, -
(i) in that part of any pipeline under the control of the occupier having control of the site, which is within 500 metres of that site and connected to it;
(ii) at any other site under the control of the same occupier any part of the boundary of which is within 500 meters of the said site; and
(iii) in any vehicle, vessel, aircraft or hovercraft, under the control of the same occupier which is used for storage purpose either at the site or within 500 metres of it. But no account shall be taken of any hazardous chemical which is in a vehicle, vessel, aircraft or a hovercraft used for transporting it.
34 S.No Chemicals Threshold Quantities (tonnes) 1 [For application of rules 4,5,7,8,13 and 15] 2[ For application of rules 10,11 and 12] 1 2 3 4
1. Acrylonitrile 350 5,000
2. Ammonia 60 600
3. Ammonium nitrate (a) 350 2,500
4. Ammonium nitrate fertilizers (b) 1,250 10,000
5. Chlorine 10 25
6. Flammable gases as defined in Schedule 1, paragraph (b) (i) 50 3000 3[7. Extremely flammable liquids as defined in Schedule 1, paragraph (b) (2) 5,000 5,000]
8. Liquid oxygen 200 2000
9. Sodium chlorate 25 250
10. Sulphur dioxide 20 500
11. Sulphur trioxide 15 100
12. Carbonyl chloride 0.750 0.750 1 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018 for “ For application of rules 4,5,7 and 8”.
2 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018 for “ For application of rules 10 to 15”.
3 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018.
35 S.No Chemicals Threshold Quantities (tonnes) 1 [For application of rules 4,5,7,8,13 and 15] 2[ For application of rules 10,11 and 12] 1 2 3 4
13. Hydrogen Sulphide 5 50
14. Hydrogen Fluoride 5 50
15. Hydrogen Cyanide 5 20
16. Carbon disulphide 20 200
17. Bromine 50 500
18. Ethylene oxide 5 501
19. Propylene oxide 5 50
20. 2-Propenal (Acrolein) 20 200
21. Bromomethane (Methyl bromide) 20 200
22. Methyl isocyanate 0.150 0.150
23. Tetraethyl lead or tetramethyl lead 5 50
24. 1,2 Dibromoethane .(Ethylene dibromide) 5 50
25. Hydrogen chloride (liquiefied gas) 25 250
26. Diphenyl methane di-isocyanate (MDI) 20 200
27. Toluene di-isocyanate (TDI) 10 100 3 [28. Very highly flammable liquids as defined in Schedule 1, paragraph (b) (3) 7,000 7,000
29. Highly flammable liquids as defined in Schedule 1, paragraph (b) (4) 10,000 10,000
30. Flammable liquids as defined in Schedule -1, paragraph (b)
(5) 15,000 1,00,000] 3 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018.
36
Explanations :
(a) This applies to ammonium nitrate and mixtures of ammonium nitrate where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight and to aqueous solutions of ammonium nitrate, where the concentration of ammonium nitrate is greater than 90 per cent by weight.
(b) This applies to straight ammonium nitrate fertilizer and to compound fertilizers, where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight (a compound fertilizer contains ammonium nitrate together with phosphate and/or potash).
37
SCHEDULE 3 [See Rule 2(a)(iii), 6 (1) (a) and (b)] LIST OF HAZARDOUS CHEMICALS FOR APPLICATION OF RULES 5 AND 7 TO 15
(a) The quantities set out below relate to each installation or group of installations belonging to the same occupier where the distance between the installations is not sufficient to avoid, in foreseeable circumstances, any aggravation of major-accident hazards. These quantities apply in any case to each group of installations belonging to the same occupier where the distance between the installations is less than 500 metres.
(b) For the purpose of determining the threshold quantity of a hazardous chemical in an industrial installation, account shall also be taken of any hazardous chemicals, which is,-
(i) in that part of any pipeline under the control of the occupier having control of the site, which is within 500 metres off that site and connected to it;
(ii) at any other site under the control of the same occupier any part of the boundary of which is within 500 metres of the said site ; and
(iii) in any vehicle, vessel, aircraft or hovercraft under the control of the same occupier which is used for storage purpose either at the site or within 500 metres of it. But no account shall be taken of any hazardous chemical which is in a vehicle, vessel, aircraft or hovercraft used for transporting it.
38
PART -I NAMED CHEMICALS S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5) GROUP 1-TOXIC CHEMICALS
1. Aldicarb 100kg 116-06-3
2. 4-Aminodiphenyl 1 kg 92-67-1
3. Amiton 1 kg 78-53-5
4. Anabasine 100 kg 494-52-0
5. Arseinc pentoxide, Arsenic (V) acid & salts 500 kg
6. Arsenic trioxide, Arsenic (III) acid & salts 100 kg
7. Arsine (Arsenic hydride) 10kg 7784-42-1
8. Azinphos-ethyl 100kg 2642-71-9
9. Azinphos-methyl 100 kg 86-50-0
10. Benzidine 1 kg 92-87-5
11. Bezidine salts 1 kg
12. Beryllium (powders, compounds) 10 kg
13. Bis (2-chloroethyl) sulphide 1 kg 505-60-2
14. Bis (chloromethyl) ether 1 kg 542-88-1
15. Carbofuran 100 kg 1563-66-2
16. Carbophenothion 100 kg 786-19-6
17. Chlorfenvinphos 100 kg 470-90-6 39 S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5)
18. 4-(Chloroformyl) morpholine 1 kg 15159-40-7
19. Chloromethyl methyl ether 1 kg 107-30-2
20. Cobalt metal, oxides, (carbonates, sulphides) as powders 1 tonne
21. Crimidine 100 kg 535-89-7
22. Cynthoate 100 kg 3734-95-0
23. Cycloheximide 100 kg 66-81-9
24. Demeton 100 kg 8065-48-3
25. Dialifos 100 kg 10311-84-9
26. OO-Diethyl S-ethylsulphonylmethyl phosphorothioate 100 kg 2588-05-8
27. OO-Diethyl S-ethylsulphonylmethyl phosphorothioate 100 kg 2588-06-9
28. OO-Diethyl S-ethylthiomethyl Phosphorodithioate 100 kg 2600-69-3
29. OO-Diethyl S-isoprophylthiomethyl phosphorodiothioate 100 kg 78-52-4
30. OO-Diethyl S-propylthiomethyl phosphorothioate 100 kg 3309-68-0
31. Dimefox 100 kg 115-26-4
32. Dimethylcarbamoyl chloride 1 kg 79-44-7
33. Dimethylnitrosamine 1 kg 62-75-9
34. Dimethyl phosphoromidocynicidic acid 1 tonne 63917-41-9
35. Diphacinone 100 kg 82-66-6 40 S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5)
36. Disulfoton 100 kg 298-04-4
37. EPN 100 kg 2104-64-5
38. Ethion 100 kg 563-12-2 39 Fensulfothion 100 kg 115-90-2
40. Fluentil 100 kg 4301-50-2
41. Fluoroacetic acid 1 kg 144-49-0
42. Fluoroacetic acid, salts 1 kg
43. Fluoroacetic acid, esters 1 kg
44. Fluoroacetic acid, amides 1 kg
45. 4-Fluorobutyric acid 1 kg 462-23-7
46. 4-Fluorobutyric acid, salts 1 kg
47. 4-Fluorobutyric acid, esters 1 kg
48. 4-Fluorobutyric acid, amides 1 kg
49. 4-Fluorocrotonic acid 1 kg 37759-72-1
50. 4-Fluorocrotonic acid, salts 1 kg
51. 4-Fluorocrotonic acid, esters 1 kg
52. 4-Fluorocrotonic acid, amides 1 kg
53. 4-Fluoro-2-hydroxybutyric acid 1 kg
54. 4-Fluoro-2-hydroxybutyric acid, salts 1 kg
55. 4-Fluoro-2-hydroxybutyric acid, esters 1 kg
56. 4-Fluoro-2-hydroxybutyric acid, amides 1 kg
57. Glycolonitrile (Hydroxyacetonitrile ) 100 kg 107-16-4
58. 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 100 kg 19408-74-3 41 S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5)
59. Hexamathylphosphoramide 1 kg 680-31-9
60. Hydrogen selenide 10 kg 7783-07-5
61. Isobenzan 100 kg 297-78-9
62. Isodrin 100 kg 465-73-6
63. Juglone (5-Hydroxynaphthalene 1,4 dione) 100 kg 481-39-0
64. 4,4-Methylenebis (2-chloroniline) 10 kg 101-14-4
65. Mthyl isocynate 150 kg 150kg 624-83-9
66. Mevinphos 100 kg 7786-34-7
67. 2-Naphthylamine 1 kg 91-59-8
68. Nickel metal, oxides, carbonates, sulphide, as powders 1 tonne
69. Nickel tetracarbonyl 10 kg 13463-39-3
70. Oxygendisulfoton 100 kg 2497-07-6
71. Oxygen difluoride 10 kg 7783-41-7
72. Paraxon (Diethyl 4-nitrophenyl phosphate) 100 kg 311-45-5
73. Parathion 100 kg 56-38-2
74. Parathion-methyl 100 kg 298-00-0
75. Pentaborane 100 kg 19624-22-7
76. Phorate 100 kg 100 kg 298-02
77. Phosacetim 100 kg 4104-14-8
78. Phosgene (carbonyl chloride) 750 kg 750kg 75-44-5
79. Phosphamidon 100 kg 13171-21-6 42 S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5)
80. Phosphine (Hydrogen phosphide) 100 kg 7803-51-2
81. Promurit [1-(3,4 dichlorophenyl)-3 triazenthiocarboxamide] 100 kg 5836-73-7
82. 1,3-Propanesultone 1 kg 1120-71-4
83. 1-Propen-2-chloro-1,3diol diacetate 10 kg 10118-72-6
84. Pyrazoxon 100 kg 108-34-9
85. Selenium hexafluoride 10 kg 7783-79-1
86. Sodium selenite 100 kg 10102-18-8
87. Stibine (Antimony hydride) 100 kg 7803-52-3
88. Sulfotop 100 kg 3689-24-5
89. Sulphur dichloride 1 tonne 10545-99-0
90. Tellurium hexafluoride 100 kg 7783-80-4
91. TEPP 100 kg 107-49-3
92. 2,3,7,8,-Tetrachlorodibenzo-p-dioxin (TCDD) 1 kg 1746-01-6
93. Tetramethylenedisulphotetramine 1 kg 80-12-6
94. Thionazin 100 kg 297-97-2
95. Tripate(2,4-Dimethyl-1,3-dithiolane-2- carboxaldehyde, O-methylcarbamoyloxime) 100 kg 26419-73-8
96. Trichloromethanesulphonyl chloride 100 kg 594-42-3
97. 1-Tri (cyclohexyl) stannyl 1H 100 kg 41083-11-8
98. Triethylenemelamine 10 kg 51-18-3
99. Warfarin 100 kg 81-81-2 43 S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5) GROUP -2 TOXIC SUBSTANCES 100 Acetone cyanohydrin (2-Cyanopropan-2-ol) 200 tonnes 75-86-5 101 Acrolein (2-Propenal) 20 tonnes 3[200 tonnes] 107-02-8 102 Acrylonitrile 20 tonnes 200 tonnes 107-13-1 103 Allyl alcohol (2-Propen-1-ol) 200 tonnes 107-18-6 104 Allylamine 200 tonnes 107-11-9 105 Ammonia 50 tonnes 500 tonnes 7664-41-7 106 Bromine 40 tonnes 1[200 tonnes] 7726-95-0 107 Carbon disulphide 20 tonnes 200 tonnes 75-15-0 108 Chlorine 10 tonnes 25 tonnes 7782-50-5 109 Diphneylmethane di-isocynate (MDI) 20 tonnes 1[200tonnes] 101-68-8 110 Ethylene dibromide (1,2-Dibromoethane) 5 tonnes 1[50 tonnes] 106-93-4 111 Ethyleneimine 50 tonnes 151-56-4 112 Formaldehyde (concentration ≥90%) 5 tonnes 1[50 tonnes] 50-00-0 113 Hydrogen chloride (liquified gas) 25 tonnes 250 tonnes 7647-01-0 114 Hydrogen cyanide 5 tonnes 20 tonnes 74-90-8 115 Hydrogen fluoride 5 tonnes 50 tonnes 7664-39-3 116 Hydrogen sulphide 5 tonnes 50 tonnes 7783-06-4 117 Methyl bromide (Bromomethane) 20 tonnes 1[200 tonnes] 74-83-9 118 Nitrogen oxides 50 tonnes 11104-93-1 119 Propylineimine 50 tonnes 75-55-8 120 Sulphur dioxide 20 tonnes 250 tonnes 7446-09-5 44 S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5) 121 Sulphur trioxide 15 tonnes 75 tonnes 7446-11-9 122 Tetraethyl lead 5 tonnes 78-00-2 123 Tetra methyl lead 5 tonnes 1[200 tonnes] 75-74-1 124 Toluene di-isocynate (TDI) 10 tonnes 100 tonnes 584-84-9 GROUP 3-HIGHLY REACTIVE CHEMICALS 125 Acetylene (ethyne) 5 tonnes 74-86-2 126 a. Ammonium nitrate (1) b. Ammonium nitrate in form of fertiliser (2) 350 tonnes 2500 tonnes 6484-52-2 1250 tonnes 127 2,2 Bis (tert-butylperoxy) butane) (concentration ≥70%) 5 tonnes 2167-23-9 128 1, 1-Bis(tert-butylperoxy) cyclohexane (concentration ≥80%) 5 tonnes 3006-86-8 129 tert-Butyl proxyacetate(concentration≥70% ) 5 tonnes 107-71-1 130 tert-Butyle peroxy isobutyrate (concentration≥ 80%) 5 tonnes 109-13-7 131 Tert-Butyl peroxy isopropyl carbonate (concentration ≥80%) 5 tonnes 2372-21-6 132 Tert-Butyl peroxymaletate (concentration ≥80%) 5 tonnes 1931-62-0 133 Tert-Butyl peroxypivalate (concentration ≥77%) 50 tonnes 927-07-1 134 Dibenzyl peroxydicarbonate (concentration≥90%) 5 tonnes 2144-45-8 45 S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5) 135 Di-sec-butyl peroxydicarbonate (concentration ≥80%) 5 tonnes 19910-65-7 136 Diethyl peroxydicarbonate (concentration ≥30% ) 50 tonnes 14666-78-5 137 2,2-dihydroperoxypropane (concentration≥30%) 5 tonnes 2614-76-08 138 di-isobutyrl peroxide (concentration ≥50%) 50 tonnes 3437-84-1 139 Di-n-propyl peroxydicarbonate (concentration≥80%) 5 tonnes 16066-38-9 140 Ethyene oxide 5 tonnes 50tonnes 75-21-8 141 Ethyl nitrate 50 tonnes 625-58-1 142 3,3,6,6,9,9 Hexamethyl - 1,2,4 5- tetroxacyclononane (concentration ≥75%) 50 tonnes 22397-33-7 143 Hydrogen 2 tonnes 50 tonnes 1333-74-0 144 Liquid Oxygen 200 tonnes 2000tonnes 7782-44-7 145 Methyl ethyl ketone peroxide (concentration ≥60%) 5 tonnes 5 tonnes 1338-23-4 146 Methyl isobutyl ketone peroxide (concentration ≥60%) 50 tonnes 37206-20-5 147 Peracetic acid (concentration ≥60%) 50 tonnes 79-21-0 148 Propylene oxide 5 tonnes 5 tonnes 75-56-9 149 Sodium chlorate 25 tonnes 7775-09-9 46 S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5) GROUP 4-EXPLOSIVE CHEMICALS 150 Barium azide 1[100 kg] 18810-58-7 151 Bis(2,4,6 -trinitrophenyl) amine 50 tonnes 131-073-7 152 Chlorotrinitro benzene 50 tonnes 28260-61-9 153 Cellulose nitrate (containing 12.6% Nitrogen) 50 tonnes 9004-70-0 154 Cyclotetramethyleneteranitramine 50 tonnes 2691-41-0 155 Cyclotrimethylenetiraniramine 50 tonnes 121-82-1 156 Diazodinitrophenol 10 tonnes 7008-81-3 157 Diethylene glycol dinitrate 10 tonnes 693-21-0 158 Dinitrophenol, salts 50 tonnes 159 Enthylene glycol dinitrate 10 tonnes 628-96-6 160 1-Guanyl-4-nitrosaminoguynyl-1-tetrazene 1[100 kg] 109-27-3 161 2, 2', 4, 4', 6, 6', -Hexanitrostilbene 50 tonnes 20062-22-0 162 Hydrazine nitrate 50 tonnes 13464-97-6 163 Lead azide 1[100 kg] 13424-46-9 164 Lead Styphnate (Lead 2,4,6- trinitroresorcinoxide) 1[100 kg] 15245-44-0 165 Mercury fulminate 1[100 kg] 628-86-4 166 N-Methyl-N,2,4,6-tetranitroaniline 50 tonnes 479-45-8 167 Nitroglycerine 10 tonnes 10 tonnes 55-63-0 168 Pentaerythritol tetra nitrate 50 tonnes 78-11-5 169 Picric acid, (2,4,6-Trinitrophenol) 50 tonnes 88-89-1 officers Typewritten text 1 Ins. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018.
47 S.
No.
Chemicals Threshold Quantity for application of Rules 5,7,8,13 and 15 for application of Rules 10 to 12 CAS Number *
(1) (2) (3) (4) (5) 170 Sodium picramate 50 tonnes 831-52-7 171 Styphnic acid (2,4,6-Trinitroresorcinol) 50 tonnes 82-71-3 172 1,3,5-Triamino-2,4,6-Trinitrobezene 50 tonnes 3058-38-6 173 Trinitroaniline 50 tonnes 26952-42-1 174 2,4,6-Trinitroanisole 50 tonnes 606-35-9 175 Trinitrobenze 50 tonnes 25377-32-6 176 Trinitrobenzoic acid 50 tonnes 35860-50-5 177 Trinitrocresol 50 tonnes 28905-71-7 178 2,4,6-Trinitrophenetole 50 tonnes 4732-14-3 179 2,4,6-Trinitrotoluene 50 tonnes 50 tonnes 118-96-7 * CAS Number (Chemical Abstract Service Number) means the number assigned to the chemical by the chemical abstracts service.
48 1[PART II CLASSES OF SUBSTANCES AS DEFINED IN PART – I, SCHEDULE –1 AND NOT SPECIFICALLY NAMED IN PART –I S.No. Classes of Chemicals For application of rules 4,5,7,8,13 and 15(Tonnes) For application of rules 10,11 and 12(Tonnes) 1 2 3 4 GROUP 5 - Flammable Chemicals
1. Flammable Gases 15 200
2. Extremely flammable liquids 1000 5000
3. Very highly flammable liquids 1500 10000
4. Highly Flammable liquids which remains liquid under pressure 25 200
5. Highly Flammable liquids 2500 20000
6. Flammable liquids 5000 50000 ]
Explanations:
(1) This applies to ammonium nitrate and mixtures of ammonium nitrate, where the nitrogen content derived from the ammonium nitrate is greater than 28% by weight and aqueous solutions of ammonium nitrate, where the concentration of ammonium nitrate is greater than 90% by weight.
(2) This applies to straight ammonium fertilizers and to compound fertilizers where the nitrogen content derived from the ammonium nitrate is greater than 28% by weight ( a compound fertilizer contains ammonium nitrate together with phosphate or potash).
__________________________________________________________________________________
1Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018.
49
SCHEDULE -4 (See Rule 2(b) (i)) INDUSTRIAL INSTALLATION WITHIN THE MEANING OF RULE 2(b)(i)
1. Installations for the production, processing or treatment of organic or inorganic chemicals using for this purpose, among others:
(a) alkylation
(b) Amination by ammonolysis
(c) carbonylation
(d) condensation
(e) dehydrogenation
(f) halogenation and manufacture of halogens
(g) esterification
(h) hydrogenation
(i) hydrolysis
(j) Oxidation
(k) Polymerziation
(l) Sulphonation
(m) desulphurization, manufacture and transformation of sulphur containing compounds
(n) nitration and manufacture of nitrogen containing compounds
(o) manufacture of phosphorous-containing compounds
(p) formulation of pesticides and of pharmaceutical products
(q) distillation
(r) extraction
(s) solvation
(t) mixing
2. Installations for distillation, refining or other processing of petroleum or petroleum products.
3. Installations for the total or partial disposal of solid or liquid chemicals by incineration or chemical decomposition.
4. Installations for the 1[production, processing, use] or treatment of energy gases, for example, LPG, PNG, SNG.
5. Installation for the dry distillation of coal or lignite.
6. Installations for the production of metals or non-metals by a wet process or by means of electrical energy.
_____________________________________________________________________________________ 1 Subs. by G.O. Ms. No. 61, Labour and Employment (M-2), dated the 24th May, 2018 for “production, processing”.
50
SCHEDULE 5 FORMAT MATERIAL SAFETY DATA SHEET (See rules 3 (2) and (3) )
1. IDENTITY OF MATERIAL Product Name Chemical Designation Trade Name Synonyms Formula Label: Category Class CAS Number UN Number Regulated Identification Shipping Name Codes / Label HAZCHEM Code:
Hazardous waste Identification Number Hazardous Ingredients CAS Number
1.
2.
3.
4.
2. PHYSICAL AND CHEMICAL PROPERTIES Physical State (Gas-, Liquid-, Solid-) Boiling Point in degree C Vapour pressure at 35 degree C--------------- mm.Hg.
Appearance Melting / Freezing point in degree C Evaporation rate at 30 degree C Odour Vapour Density Solubility in water at 30 degree C (air – 1) Others Specific Gravity PH (Corrosivity, etc., (Water – 1)
3. FIRE AND EXPLOSIVE HAZARDS DATA Explosion / Flammability Flash Point (deg.) C LEL % Auto ignition Temperature degree C Flash Point (deg.) C LEL % TDG Flammability (Classification)
4. REACITIVE HAZARDS Impact (hazardous Combustion products) Stability to Static Discharge (hazardous decomposition products) Reactivity (Conditions to avoid) 51 Hazardous Polymerisation May / May not occur (Conditions to avoid) Incompatibility (Materials to avoid)
5. HEALTH HAZARD DATA Routes of Entry: (Inhalation, skin, mucus membranes and eye contact and ingestion).
Effects of Exposure / Symptoms:
LD 50 ( in rat) Orally or percutaneous absorption LC 50 (mg/kg body Weight) (in rat) (mg /l)/4 hours.
Permissible Exposure Limit (PEL) PPM mg / cu.m Short term ppm mg/cu.m.
Exposure Limit (STEL) Threshold Limit PPM mg/cu.m Value (TLV) of ACGIH PPM mg / cu.m Odour Threshold ppm mg/cu.m.
Emergency Treatment:
6. HAZARD SPECIFICATION NEPA Health Flammability Stability Special HAZARD Signal Known Hazards:
Combustible Liquid Water Reactive Material Irritant Flammable Material Oxidiser Sensitizer Pyrophoric Material Organic peroxide Carcinogen Explosive Material Corresive Material Mutagen Unstable Material Compressed Gas Other (Specify)
7. SAFE USAGE DATA Ventilation General / Mechanical Local Exhaust Eyes (Specify) Protective Respiratory (Specify) Equipment (Gloves (Specify) Required Clothing (Specify) Other (Specify) Precautions Handling & Storage Others (Specify) 52
8. EMERGENCY RESPONSE DATA Fire Extinguishing Media Fire Special Procedures Unusual Hazards Exposure (Inhalation, skin and eye contact, First Aid Measures ingestion) Spills Steps to be taken Waste Disposal Method
9. ADDITIONAL INFORMATION
10. SOURCES USED Reference to books, journals, etc.,
11. MANUFACTURE / SUPPLIER DATA Firm’s Name Standard packing Mailing Address ------------------------- Telephone Number Other Telex Number Other Telegraphic Address ----------------------- Contact person in Emergency Emergency Telephone in Transit areas.
Acronyms and Glossary of terms:
CAS: Chemical Abstract Service Registration Number UN Number: United Nations Number.
HAZCHEM Code: Emergency Action Code (EAC), allocated by the Joint Committee of Fire Brigade Operations, U.K.
TDG Flammability: Transport of Dangerous Goods-- Flammability Classification by United Nations.
NEPA: Nation Fire Protection Association USA.
53 LD50 and LC 50 represent the dose in mg/kg/ of body weight and the concentration in mg/l for 4 hours having lethal effect on 50% of the animals (rats) treated.
PEL: Permissible Exposure Limit as laid down in the statutes.
TVL: Threshold Limit Value as laid down by the American Conference of Governmental Industrial Hygienists (ACGIH) USA.
STEL: Short Term Exposure Limit as laid down in the statutes or by the ACGIH.
GUIDELINES:
All efforts should be made to fill in all the columns. No column should be left blank. In case certain information is applicable or available, N/App. or N/Av. sign should be used.
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SCHEDULE -6 [See Rule 5(1)] INFORMATION TO BE FURNISHED REGARDING NOTIFICATION OF A MAJOR ACCIDENT Report number ………………………………… of the particular accident.
1. General data a) Name of the site b) Name and address of the occupier (Also state telephone/telex number) c) i. Registration number ii. Licence number (as may have been allotted under any status applicable to the site, e.g.the Factories Act) d) i. Nature of industrial activity (Mention what is actually manufactured, stored etc.)
ii. National Industrial Classification, 1987 at the four digit level.
2. Type of major accident Explosion Fire Emission of hazardous chemicals
3. Description of the major accident.
(a) Date, shift and hour of the accident
(b) Department/Section and exact place where the accident took place
(c) The process/operation undertaken in the Department / Section where the accident took place.
(attach a flow chart, if necessary)
(d) The circumstances of the accident and the hazardous chemicals involved
4. Emergency Measures taken and measures envisaged to be taken to alleviate short term effects of the accident.
5. Causes of the major accident.
Known (to be specified) …………… Not Known …………… Information will be supplied as soon as possible ……………
6. Nature and extent of damage
(a) Within establishment - casualties …………… Killed …………… Injured …………… Poisoned 55 -Persons exposed to the major accident …………… -material damaged …………… -damage is still present …………… -danger no longer exists. ……………
(b) Outside establishment -casualties. …………… Killed …………… Injured …………… Poisoned Persons exposed to the major accident ……………………………………… -material damaged …………… -damage is still present …………… -danger no longer exists …………… -damage to environment ……………
7. Data available for assessing the effects of the accident on persons and environment.
8. Steps already taken or envisaged
(a) to alleviate medium or long term effects of the accident
(b) to prevent recurrence of similar major accident
(c) Any other relevant information.
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SCHEDULE -7 [ See Rule 7(1)and 9(b)] 1[INFORMATION TO BE FURNISHED FOR THE NOTIFICATION OF SITE] Particulars to be included in a notification of site
1. The name and address of the occupier making the notification.
2. The full postal address of the site where the notifiable industrial activity will be carried on.
3. The area of the site covered by the notification and of any adjacent site which is required to be taken into account by virtue of Schedule 2(b) and Schedule 3(b).
4. The date on which it is anticipated that the notifiable industrial activity will commence or if it has already commenced a statement to that effect.
5. The name and maximum quantity liable to be on the site of each hazardous chemical for which notification is being made.
6. Organisation structure, namely, organisation diagram for the proposed industrial activity and set up for ensuring safety and health.
7. Information relating to the potential for major accidents, namely-
(a) identification of major accident hazards;
(b) the conditions or events which could be significant in brining one about;
(c) brief description of the measures taken.
8. Information relating to the site namely:-
(a) a map of the site and its surrounding area to a scale large enough to show any features that may be significant in the assessment of the hazard or risk associated with the site;
(i) area likely to be affected by the major accident.
(ii) Population distribution in the vicinity.
(b) a scale plan of the site showing the location and quantity of all significant inventories of the hazardous chemicals;
(c) a description of the processes or storage involving the hazardous chemicals, the maximum amount of such a hazardous chemical in the given process or storage and an indication of the conditions under which it is normally held;
(d) the maximum number of persons likely to be present on site.
9. The arrangement for training of workers and equipment necessary to ensure safety of such workers.
1 Subs. by G.O. Ms. No. 17, Labour and Employment (M-2), dated the 21st February, 2008. (deemed to have come into force on 16th July, 2008), for the heading “Information to be furnished for the notification of activities sites”.
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SCHEDULE 8 [See rule 10 (1)] INFORMATION TO BE FURNISHED IN A SAFETY REPORT
1. The name and address of the person furnishing the information.
2. Description of the industrial activity, namely:
(a) site,
(b) construction design,
(c) protection zones (explosion protection, separation distances),
(d) accessibility of plant,
(e) maximum number of persons working on the site and particularly of those persons exposed to the hazard.
3. Description of the processes, namely —
(a) technical purpose of the industrial activity,
(b) basic principles of the technological process,
(c) process and safety-related data for the individual process stages,
(d) process description,
(e) safety-related types of utilities.
4. Description of the hazardous chemicals, namely —
(a) chemicals (quantities, substance data on physical and chemical properties, safety-related data on explosive limits, flash-point, thermal stability, toxicological data and threshold limit values, lethal concentration),
(b) the form in which the chemicals may occur on into which they may be transformed in the event of abnormal conditions,
(c) the degree of purity of the hazardous chemicals.
5. Information on the preliminary hazard analysis, namely —
(a) types of accident,
(b) system elements or foreseen events that can lead to a major accident,
(c) hazards,
(d) safety-relevant components.
6. Description of safety-relevant units, among others ;
(a) special design criteria,
(b) controls and alarms,
(c) pressure relief systems,
(d) quick-acting valves,
(e) collecting tanks / dump tanks,
(f) sprinkler systems,
(g) fire protection.
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7. Information of the hazard assessment, namely :
(a) identification of hazards,
(b) the causes of major accidents,
(c) assessment of hazards according to their occurrence frequency,
(d) assessment of accident consequences,
(e) safety systems,
(f) known accident history.
8. Description of information on organisational system used to carry on the industrial activity safety, namely :
(a) maintenance and inspection schedules,
(b) guidelines for the training of personnel,
(c) allocation and delegation of responsibility for plant safety,
(d) implementation of safety procedures.
9. Information on assessment of the consequences of major accidents, namely :
(a) assessment of the possible release of hazardous chemicals or of energy,
(b) possible dispersion of released chemicals,
(c) assessment of the effects of the releases (size of the affected area, health effects, property damage).
10. Information on the mitigation of major accidents, namely : —
(a) fire brigade,
(b) alarm systems,
(c) emergency plan containing system of organisation used to fight the emergency, the alarm and the communication routes, guidelines for fighting the emergency, examples of possible accident sequences,
(d) co-ordination with the District Collector or the District Emergency authority and its off-site emergency plan,
(e) notification of the nature and scope of the hazard in the event of an accident.
(f) antidotes in the event of a release of a hazardous chemical.
59 1[SCHEDULE 9] [See rule 13(1)] Details to be furnished in the on-site emergency plan
1. Name and address of the person furnishing the information:
2. Key personnel of the organisation and responsibilities assigned to them in case of an emergency:
3.
(a)
(b) Outside organisanions if involved in assisting during on-site emergency — Type of accidents.
Responsibility assigned.
4. Details of liaison arrangement between the organisations:
5. Information on the preliminary hazard analysis —
(a)
(b)
(c)
(d) Type of accidents.
System elements or events that can lead to a major accident.
Hazards.
Safety relevant components.
6. Details about the site —
(a)
(b)
(c) Location of dangerous substances.
Seat of key personnel.
Emergency control room.
7. Description of hazardous chemicals at plant site — a)
(b)
(c) Chemicals (quantities and toxicological data).
Transformation if any which could occur Purity of hazardous chemicals.
8. Likely dangers to the plant:
1 Schedule 9 added by GO. No. 17, Labour and Employment (M-2), dated the 21st February, 2008 (deemed to have come into force on 16th July, 2008).
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9.
Enumerate effects of,--
(a) Stress and strain caused during normal operation;
(b) fire and explosion inside the plant and effect if any, of fire and explosion outside.
10.
Details regarding,--
(a)
(b)
(c)
(d)
(e)
(f) warning alarm and safety and security systems , alarm and hazard control plans in line with disaster control and hazard control planning, ensuring the necessary technical and organizational precautions , reliable measuring instruments, control units and servicing of such equipments ;
precautions in designing the foundation and load-bearing parts of the building , continuous surveillance of operations , maintenance and repair work according to generally rules of good engineering practices ,
11. Details of communication facilities available during emergency and those required for an off-site emergency
12. Details of fire-fighting and other facilities available and those required for an off-site emergency
13. Details of first aid and hospital services available and its adequacy:
SCHEDULE 3 NAMED CHEMICALS CLASSES OF SUBSTANCES AS DEFINED IN PART – I, SCHEDULE –1 AND NOT SPECIFICALLY NAMED IN PART –I